In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure | Sciact - CRIS-система Института катализа

In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure Научная публикация

Журнал

Energy and Fuels
ISSN: 0887-0624 , E-ISSN: 1520-5029

Вых. Данные

Год: 2014, Том: 28, Страницы: 6315-6321 Страниц : 7 DOI: 10.1021/ef5015549

Ключевые слова

Crude oil; Electrospinning; Magnetic moments; Molecular dynamics; Molecules; Oil shale; Oil wells; Petroleum deposits; Spin dynamics

Авторы

Trukhan Sergey N. ^1,2,3 , Yudanov Valerii F. ¹ , Gabrienko Anton A. ⁴ , Subramani Velu ⁵ , Kazarian Sergei G. ⁴ , Martyanov Oleg N. ^1,2

Организации

1	Boreskov Institute of Catalysis, 5 Academican Lavrentiev Avenue, 630090 Novosibirsk, Russia
2	Novosibirsk State University, 2 Pirogov Street, 630090 Novosibirsk, Russia
3	UNICAT Limited, 5 Academican Lavrentiev Avenue, 630090 Novosibirsk, Russia
4	Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, United Kingdom
5	BP Products North America, Incorporated, Naperville, Illinois 60563, United States

Информация о финансировании (1)

Фонд «Сколково»

A comparison of the behavior of asphaltene molecules extracted from crude oil and dissolved in aromatic solvent as a model system with the behavior of vanadium-containing molecules in real crude oils via electron spin resonance in situ technique showed that the changes of rotational mobility of asphaltene molecules can be related to the changes of the local viscosity and environment of the asphaltenes as well as the characteristic sizes of vanadyl-containing fragments because of aggregation/disaggregation processes in crude oils. The information about the mobility of asphaltene molecules in different local environments at different temperatures and pressures is an important step in understanding both the aggregation of the asphaltenes and crude oil fouling processes in addition to the conditions required for the deposits to be formed.

Trukhan S.N. , Yudanov V.F. , Gabrienko A.A. , Subramani V. , Kazarian S.G. , Martyanov O.N.
In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure
Energy and Fuels. 2014. V.28. P.6315-6321. DOI: 10.1021/ef5015549 WOS Scopus РИНЦ РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	9 июл. 2014 г.
Принята к публикации:	11 сент. 2014 г.
Опубликована online:	23 сент. 2014 г.
Опубликована в печати:	16 окт. 2014 г.

Web of science:	WOS:000343336000015
Scopus:	2-s2.0-84949116531
РИНЦ:	23994735 \| 41765257
Chemical Abstracts:	2014:1522686
Chemical Abstracts (print):	161:522231
OpenAlex:	W1984481283

БД	Цитирований
Web of science	33
Scopus	36
РИНЦ	22 37
OpenAlex	37