In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure | Sciact - CRIS-system of Boreskov Institute of Catalysis

In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure Full article

Journal

Energy and Fuels
ISSN: 0887-0624 , E-ISSN: 1520-5029

Output data

Year: 2014, Volume: 28, Pages: 6315-6321 Pages count : 7 DOI: 10.1021/ef5015549

Tags

Crude oil; Electrospinning; Magnetic moments; Molecular dynamics; Molecules; Oil shale; Oil wells; Petroleum deposits; Spin dynamics

Authors

Trukhan Sergey N. ^1,2,3 , Yudanov Valerii F. ¹ , Gabrienko Anton A. ⁴ , Subramani Velu ⁵ , Kazarian Sergei G. ⁴ , Martyanov Oleg N. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, 5 Academican Lavrentiev Avenue, 630090 Novosibirsk, Russia
2	Novosibirsk State University, 2 Pirogov Street, 630090 Novosibirsk, Russia
3	UNICAT Limited, 5 Academican Lavrentiev Avenue, 630090 Novosibirsk, Russia
4	Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, United Kingdom
5	BP Products North America, Incorporated, Naperville, Illinois 60563, United States

Funding (1)

Skolkovo Foundation

A comparison of the behavior of asphaltene molecules extracted from crude oil and dissolved in aromatic solvent as a model system with the behavior of vanadium-containing molecules in real crude oils via electron spin resonance in situ technique showed that the changes of rotational mobility of asphaltene molecules can be related to the changes of the local viscosity and environment of the asphaltenes as well as the characteristic sizes of vanadyl-containing fragments because of aggregation/disaggregation processes in crude oils. The information about the mobility of asphaltene molecules in different local environments at different temperatures and pressures is an important step in understanding both the aggregation of the asphaltenes and crude oil fouling processes in addition to the conditions required for the deposits to be formed.

Trukhan S.N. , Yudanov V.F. , Gabrienko A.A. , Subramani V. , Kazarian S.G. , Martyanov O.N.
In situ Electron Spin Resonance Study of Molecular Dynamics of Asphaltenes at Elevated Temperature and Pressure
Energy and Fuels. 2014. V.28. P.6315-6321. DOI: 10.1021/ef5015549 WOS Scopus РИНЦ РИНЦ OpenAlex ANCAN

Submitted:	Jul 9, 2014
Accepted:	Sep 11, 2014
Published online:	Sep 23, 2014
Published print:	Oct 16, 2014

≡ Web of science:	WOS:000343336000015
≡ Scopus:	2-s2.0-84949116531
≡ Elibrary:	23994735 \| 41765257
≡ OpenAlex:	W1984481283
≡ Chemical Abstracts:	2014:1522686
≡ Chemical Abstracts (print):	161:522231

≡ Web of science	33	Сбор данных от 20.02.2026
≡ Scopus	36	Сбор данных от 15.02.2026
≡ Elibrary	22 37	Сбор данных от 15.02.2026
≡ OpenAlex	37	Сбор данных от 15.02.2026