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Environmentally Benign Oxidation of Alkylphenols to p-Benzoquinones: A Comparative Study of Various Ti-containing Catalysts Научная публикация

Конференция 25th Biennial Conference of the Organic-Reactions-Catalysis-Society
02-06 мар. 2014 , Westin La Paloma Resort in Tucson, AZ
Журнал Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Вых. Данные Год: 2014, Том: 57, Номер: 17-20, Страницы: 1377-1384 Страниц : 8 DOI: 10.1007/s11244-014-0306-4
Ключевые слова Alkylphenols, Heterogeneous catalysis, Hydrogen peroxide, MIL-125, Quinones, Selective oxidation, Titanium-silicate
Авторы Kholdeeva Oxana A. 1,2 , Ivanchikova Irina D. 1 , Maksimchuk Nataliya V. 1,2 , Melʹgunov Maxim S. 1,2 , Chang Jong-San 3,4 , Guidotti Matteo 5 , Shutilov Alexei A. 1 , Zajkovskii Vladimir I. 1,2
Организации
1 Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia
3 Korea Research Institute of Chemical Technology (KRICT), Gajeongro 141, Yuseong, P.O. Box 107, Daejeon 305-600, Republic of Korea
4 Department of Chemistry, Sungkyunkwan University, Suwon 440-476, Republic of Korea
5 CNR-Istituto di Scienze e Tecnologie Molecolari and Dip. Chimica IMA ‘‘L. Malatesta’’, via G. Venezian 21, 20133 Milan, Italy

Информация о финансировании (4)

1 Korea Research Institute of Chemical Technology SK-1301
2 Российский фонд фундаментальных исследований 13-03-00413
3 Российский фонд фундаментальных исследований 13-03-92699
4 National Research Council 0040734 (2013)

Реферат: Catalytic properties of Ti-containing porous solids were compared in the oxidation of 2,3,6-trimethylphenol (TMP) with H2O2 to produce 2,3,5-trimethyl-1,4-benzoquinone (TMBQ, vitamin E key intermediate). Mesoporous titanium–silicates with di(oligo)nuclear Ti centers, metal–organic framework MIL-125 and amorphous TiO2 demonstrated 100 % selectivity toward TMBQ. Titanium–silicates prepared by evaporation-induced self-assembly revealed superior performance in terms of product yield and catalyst reusability.
Библиографическая ссылка: Kholdeeva O.A. , Ivanchikova I.D. , Maksimchuk N.V. , Melʹgunov M.S. , Chang J-S. , Guidotti M. , Shutilov A.A. , Zajkovskii V.I.
Environmentally Benign Oxidation of Alkylphenols to p-Benzoquinones: A Comparative Study of Various Ti-containing Catalysts
Topics in Catalysis. 2014. V.57. N17-20. P.1377-1384. DOI: 10.1007/s11244-014-0306-4 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 3 сент. 2014 г.
Опубликована в печати: 1 нояб. 2014 г.
Идентификаторы БД:
Web of science: WOS:000344158300011
Scopus: 2-s2.0-84939788965
РИНЦ: 24954437
Chemical Abstracts: 2014:1488424
Chemical Abstracts (print): 161:568370
OpenAlex: W2002747889
Цитирование в БД:
БД Цитирований
Web of science 11
Scopus 13
РИНЦ 14
OpenAlex 11
Альметрики: