Environmentally Benign Oxidation of Alkylphenols to p-Benzoquinones: A Comparative Study of Various Ti-containing Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Environmentally Benign Oxidation of Alkylphenols to p-Benzoquinones: A Comparative Study of Various Ti-containing Catalysts Full article

Conference

25th Biennial Conference of the Organic-Reactions-Catalysis-Society
02-06 Mar 2014 , Westin La Paloma Resort in Tucson, AZ

Journal

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Output data

Year: 2014, Volume: 57, Number: 17-20, Pages: 1377-1384 Pages count : 8 DOI: 10.1007/s11244-014-0306-4

Tags

Alkylphenols, Heterogeneous catalysis, Hydrogen peroxide, MIL-125, Quinones, Selective oxidation, Titanium-silicate

Authors

Kholdeeva Oxana A. ^1,2 , Ivanchikova Irina D. ¹ , Maksimchuk Nataliya V. ^1,2 , Melʹgunov Maxim S. ^1,2 , Chang Jong-San ^3,4 , Guidotti Matteo ⁵ , Shutilov Alexei A. ¹ , Zajkovskii Vladimir I. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia
3	Korea Research Institute of Chemical Technology (KRICT), Gajeongro 141, Yuseong, P.O. Box 107, Daejeon 305-600, Republic of Korea
4	Department of Chemistry, Sungkyunkwan University, Suwon 440-476, Republic of Korea
5	CNR-Istituto di Scienze e Tecnologie Molecolari and Dip. Chimica IMA ‘‘L. Malatesta’’, via G. Venezian 21, 20133 Milan, Italy

Funding (4)

1	Korea Research Institute of Chemical Technology	SK-1301
2	Russian Foundation for Basic Research	13-03-00413
3	Russian Foundation for Basic Research	13-03-92699
4	National Research Council	0040734 (2013)

Catalytic properties of Ti-containing porous solids were compared in the oxidation of 2,3,6-trimethylphenol (TMP) with H2O2 to produce 2,3,5-trimethyl-1,4-benzoquinone (TMBQ, vitamin E key intermediate). Mesoporous titanium–silicates with di(oligo)nuclear Ti centers, metal–organic framework MIL-125 and amorphous TiO2 demonstrated 100 % selectivity toward TMBQ. Titanium–silicates prepared by evaporation-induced self-assembly revealed superior performance in terms of product yield and catalyst reusability.

Kholdeeva O.A. , Ivanchikova I.D. , Maksimchuk N.V. , Melʹgunov M.S. , Chang J-S. , Guidotti M. , Shutilov A.A. , Zajkovskii V.I.
Environmentally Benign Oxidation of Alkylphenols to p-Benzoquinones: A Comparative Study of Various Ti-containing Catalysts
Topics in Catalysis. 2014. V.57. N17-20. P.1377-1384. DOI: 10.1007/s11244-014-0306-4 WOS Scopus РИНЦ ANCAN OpenAlex

Published online:	Sep 3, 2014
Published print:	Nov 1, 2014

Web of science:	WOS:000344158300011
Scopus:	2-s2.0-84939788965
Elibrary:	24954437
Chemical Abstracts:	2014:1488424
Chemical Abstracts (print):	161:568370
OpenAlex:	W2002747889

DB	Citing
Web of science	11
Scopus	13
Elibrary	14
OpenAlex	12