Pd-PEPPSI Complexes Based on 1,2,4-triazol-3-ylidene ligands as Efficient Catalysts in the Suzuki—Miyaura Reaction Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2018, Volume: 67, Number: 1, Pages: 79-84 Pages count : 6 DOI: 10.1007/s11172-018-2040-8 | ||||||
| Tags | Nheterocyclic carbenes, 1,2,4triazoles, Suzuki—Miyaura crosscoupling, catalysis, palladium complexes | ||||||
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Abstract:
The palladium complexes of the Pd-PEPPSI type with N-heterocyclic carbenes of the 1,2,4-triazole series were synthesized in 76—99% yields by the reactions of PdCl2 with 1,4-di- alkyl-1,2,4-triazolium salts in pyridine in the presence of KBr or KI as sources of halide ions and tetrabutylammonium salts as phase-transfer catalysts. The obtained complexes can be used as efficient catalysts for the Suzuki—Miyaura cross-coupling and are not inferior to the commercially available Pd-PEPPSI catalysts in activity.
Cite:
Chernenko A.Y.
, Astakhov A.V.
, Pasyukov D.V.
, Dorovatovskii P.V.
, Zubavichus Y.V.
, Khrustalev V.N.
, Chernyshev V.M.
Pd-PEPPSI Complexes Based on 1,2,4-triazol-3-ylidene ligands as Efficient Catalysts in the Suzuki—Miyaura Reaction
Russian Chemical Bulletin. 2018. V.67. N1. P.79-84. DOI: 10.1007/s11172-018-2040-8 WOS Scopus РИНЦ ANCAN OpenAlex
Pd-PEPPSI Complexes Based on 1,2,4-triazol-3-ylidene ligands as Efficient Catalysts in the Suzuki—Miyaura Reaction
Russian Chemical Bulletin. 2018. V.67. N1. P.79-84. DOI: 10.1007/s11172-018-2040-8 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Черненко А.Ю.
, Астахов А.В.
, Пасюков Д.В.
, Дороватовский П.В.
, Зубавичус Я.В.
, Хрусталев В.Н.
, Чернышев В.М.
Комплексы Pd-PEPPSI на основе 1,2,4-триазол-3-илиденовых лигандов - эффективные катализаторы реакции Сузуки-Мияуры
Известия Академии наук. Серия химическая. 2018. №1. С.79-84. РИНЦ
Комплексы Pd-PEPPSI на основе 1,2,4-триазол-3-илиденовых лигандов - эффективные катализаторы реакции Сузуки-Мияуры
Известия Академии наук. Серия химическая. 2018. №1. С.79-84. РИНЦ
Dates:
| Submitted: | Sep 11, 2017 |
| Accepted: | Oct 23, 2017 |
| Published online: | Jan 1, 2018 |
| Published print: | Apr 19, 2018 |
Identifiers:
| Web of science: | WOS:000430480200011 |
| Scopus: | 2-s2.0-85045850241 |
| Elibrary: | 35544825 |
| Chemical Abstracts: | 2018:818850 |
| Chemical Abstracts (print): | 170:534423 |
| OpenAlex: | W2802971283 |