Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation Научная публикация
| Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Вых. Данные | Год: 2021, Том: 617, Номер статьи : 118115, Страниц : 8 DOI: 10.1016/j.apcata.2021.118115 | ||
| Ключевые слова | Transfer hydrogentaion, Raney® nickel, Poisoning titration, Turnover frequency, Thiophenol | ||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 075-15-2019-1876 |
| 2 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0003 |
Реферат:
For the first time, the poisoning effect of 15 different chemical compounds on Raney® nickel catalyst has been comparatively studied in the transfer hydrogenation of camphor using 2-PrOH as a solvent and a hydrogen donor. It has been shown that thiophenol, HCl and H3PO4 demonstrate the strongest poisoning action under the reaction conditions: no camphor conversion was observed at 5 mol.% of poison-to-nickel ratio. A strong chemical binding of thiophenol molecules to the catalyst surface without Csingle bondS bond cleavage was proved by XRF, TPD methods, CHNS analysis, and FTIR spectroscopy. It was shown that the poisoning titration with thiophenol is an effective and convenient tool to calculate the number of active sites for Ni based catalysts directly, measuring catalytic activity in target chemical reaction, which was defined correspondently as 2.4 h−1 and 9.6 × 10–5 mole for Raney® nickel catalyst in the transfer hydrogenation.
Библиографическая ссылка:
Philippov A.A.
, Chibiryaev A.M.
, Yakushkin S.S.
, Gladky A.Y.
, Martyanov O.N.
Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation
Applied Catalysis A: General. 2021. V.617. 118115 :1-8. DOI: 10.1016/j.apcata.2021.118115 WOS Scopus РИНЦ CAPlus OpenAlex
Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation
Applied Catalysis A: General. 2021. V.617. 118115 :1-8. DOI: 10.1016/j.apcata.2021.118115 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 4 февр. 2021 г. |
| Принята к публикации: | 16 мар. 2021 г. |
| Опубликована online: | 24 мар. 2021 г. |
| Опубликована в печати: | 5 мая 2021 г. |
Идентификаторы БД:
| Web of science: | WOS:000643734500002 |
| Scopus: | 2-s2.0-85103551607 |
| РИНЦ: | 46772756 |
| Chemical Abstracts: | 2021:796901 |
| OpenAlex: | W3136086858 |