Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2021, Volume: 617, Article number : 118115, Pages count : 8 DOI: 10.1016/j.apcata.2021.118115 | ||
| Tags | Transfer hydrogentaion, Raney® nickel, Poisoning titration, Turnover frequency, Thiophenol | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 075-15-2019-1876 |
Abstract:
For the first time, the poisoning effect of 15 different chemical compounds on Raney® nickel catalyst has been comparatively studied in the transfer hydrogenation of camphor using 2-PrOH as a solvent and a hydrogen donor. It has been shown that thiophenol, HCl and H3PO4 demonstrate the strongest poisoning action under the reaction conditions: no camphor conversion was observed at 5 mol.% of poison-to-nickel ratio. A strong chemical binding of thiophenol molecules to the catalyst surface without Csingle bondS bond cleavage was proved by XRF, TPD methods, CHNS analysis, and FTIR spectroscopy. It was shown that the poisoning titration with thiophenol is an effective and convenient tool to calculate the number of active sites for Ni based catalysts directly, measuring catalytic activity in target chemical reaction, which was defined correspondently as 2.4 h−1 and 9.6 × 10–5 mole for Raney® nickel catalyst in the transfer hydrogenation.
Cite:
Philippov A.A.
, Chibiryaev A.M.
, Yakushkin S.S.
, Gladky A.Y.
, Martyanov O.N.
Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation
Applied Catalysis A: General. 2021. V.617. 118115 :1-8. DOI: 10.1016/j.apcata.2021.118115 WOS Scopus РИНЦ OpenAlex AN
Poisoning Titration of Metal Nickel-Based Catalysts – an Efficient and Convenient Tool to Quantify Active Sites in Transfer Hydrogenation
Applied Catalysis A: General. 2021. V.617. 118115 :1-8. DOI: 10.1016/j.apcata.2021.118115 WOS Scopus РИНЦ OpenAlex AN
Dates:
| Submitted: | Feb 4, 2021 |
| Accepted: | Mar 16, 2021 |
| Published online: | Mar 24, 2021 |
| Published print: | May 5, 2021 |
Identifiers:
| ≡ Web of science: | WOS:000643734500002 |
| ≡ Scopus: | 2-s2.0-85103551607 |
| ≡ Elibrary: | 46772756 |
| ≡ OpenAlex: | W3136086858 |
| ≡ Chemical Abstracts: | 2021:796901 |