Sciact
  • EN
  • RU

Zirconium-Containing Metal Organic Frameworks as Solid Acid Catalysts for the N-Formylation of Aniline with Formic Acid Научная публикация

Журнал Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204
Вых. Данные Год: 2021, Том: 133, Номер: 1, Страницы: 355–369 Страниц : 15 DOI: 10.1007/s11144-021-01982-1
Ключевые слова N-formylation; Aniline; Formic acid; Metal-organic framework; Bronsted acidity
Авторы Timofeeva Maria N. 1,2 , Panchenko Valentina N. 1,2 , Lukoyanov Ivan A. 1,2 , Jhung Sung Hwa 3
Организации
1 Boreskov Institute of Catalysis SB RAS
2 Novosibirsk State Technical University
3 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0008

Реферат: Porous Zr-based metal-organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 0C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.
Библиографическая ссылка: Timofeeva M.N. , Panchenko V.N. , Lukoyanov I.A. , Jhung S.H.
Zirconium-Containing Metal Organic Frameworks as Solid Acid Catalysts for the N-Formylation of Aniline with Formic Acid
Reaction Kinetics, Mechanisms and Catalysis. 2021. V.133. N1. P.355–369. DOI: 10.1007/s11144-021-01982-1 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 8 февр. 2021 г.
Принята к публикации: 18 апр. 2021 г.
Опубликована online: 27 апр. 2021 г.
Опубликована в печати: 1 июн. 2021 г.
Идентификаторы БД:
Web of science: WOS:000644761600001
Scopus: 2-s2.0-85105379436
РИНЦ: 46055354
Chemical Abstracts: 2021:980497
OpenAlex: W3157461151
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 7
РИНЦ 3
OpenAlex 8
Альметрики: