Zirconium-Containing Metal Organic Frameworks as Solid Acid Catalysts for the N-Formylation of Aniline with Formic Acid Full article
| Journal |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Output data | Year: 2021, Volume: 133, Number: 1, Pages: 355–369 Pages count : 15 DOI: 10.1007/s11144-021-01982-1 | ||||||
| Tags | N-formylation; Aniline; Formic acid; Metal-organic framework; Bronsted acidity | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
Abstract:
Porous Zr-based metal-organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 0C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order:
MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of
N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.
Cite:
Timofeeva M.N.
, Panchenko V.N.
, Lukoyanov I.A.
, Jhung S.H.
Zirconium-Containing Metal Organic Frameworks as Solid Acid Catalysts for the N-Formylation of Aniline with Formic Acid
Reaction Kinetics, Mechanisms and Catalysis. 2021. V.133. N1. P.355–369. DOI: 10.1007/s11144-021-01982-1 WOS Scopus РИНЦ AN OpenAlex
Zirconium-Containing Metal Organic Frameworks as Solid Acid Catalysts for the N-Formylation of Aniline with Formic Acid
Reaction Kinetics, Mechanisms and Catalysis. 2021. V.133. N1. P.355–369. DOI: 10.1007/s11144-021-01982-1 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Feb 8, 2021 |
| Accepted: | Apr 18, 2021 |
| Published online: | Apr 27, 2021 |
| Published print: | Jun 1, 2021 |
Identifiers:
| Web of science: | WOS:000644761600001 |
| Scopus: | 2-s2.0-85105379436 |
| Elibrary: | 46055354 |
| Chemical Abstracts: | 2021:980497 |
| OpenAlex: | W3157461151 |