Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin | Sciact - CRIS-система Института катализа

Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin Научная публикация

Журнал

Chemický průmysl
ISSN: 0009-2789

Вых. Данные

Год: 1987, Том: 37, Номер: 1, Страницы: 26-30 Страниц : 5

Ключевые слова

copper chromite catalyst reductive amination; acetone reductive amination aniline catalyst; amination reductive acetone aniline kinetics

Авторы

Kurc Ladislav ¹ , Cerveny Libor ¹ , Ruzicka Vlastimil ¹ , Yureva T.M. ² , Minjukova T.P. ²

Организации

1	Vysoka skola chemickotechnologicka, Praha
2	Institut katalyzy SO AV SSSR, Novosibisk

The acidic centers of CuCr2O4.CuO catalyzed the reductive amination of Me2CO with PhNH2. The rate of PhNHCHMe2 accumulation increased with the acidity of the catalyst surface, and was accompanied by high catalytic activity toward hydrogenation of the C:N bond of the intermediate PhN:CMe2 and low activity toward Me2CO hydrogenation. Ionic Cu catalyzed side reactions, and was undesirable.

Kurc L. , Cerveny L. , Ruzicka V. , Yureva T.M. , Minjukova T.P.
Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin
Chemický průmysl. 1987. Т.37. №1. С.26-30. CAPlusCA

Поступила в редакцию:

27 февр. 1986 г.

Chemical Abstracts:	1988:21407
Chemical Abstracts (print):	108:21407

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