Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin | Sciact - CRIS-system of Boreskov Institute of Catalysis

Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin Full article

Journal

Chemický průmysl
ISSN: 0009-2789

Output data

Year: 1987, Volume: 37, Number: 1, Pages: 26-30 Pages count : 5

Tags

copper chromite catalyst reductive amination; acetone reductive amination aniline catalyst; amination reductive acetone aniline kinetics

Authors

Kurc Ladislav ¹ , Cerveny Libor ¹ , Ruzicka Vlastimil ¹ , Yureva T.M. ² , Minjukova T.P. ²

Affiliations

1	Vysoka skola chemickotechnologicka, Praha
2	Institut katalyzy SO AV SSSR, Novosibisk

The acidic centers of CuCr2O4.CuO catalyzed the reductive amination of Me2CO with PhNH2. The rate of PhNHCHMe2 accumulation increased with the acidity of the catalyst surface, and was accompanied by high catalytic activity toward hydrogenation of the C:N bond of the intermediate PhN:CMe2 and low activity toward Me2CO hydrogenation. Ionic Cu catalyzed side reactions, and was undesirable.

Kurc L. , Cerveny L. , Ruzicka V. , Yureva T.M. , Minjukova T.P.
Aktivita mednatochromitych katalyzatoru pro hydrogenaci karbonylovych a iminovych skupin
Chemický průmysl. 1987. Т.37. №1. С.26-30. ANCAN

Submitted:

Feb 27, 1986

Chemical Abstracts:	1988:21407
Chemical Abstracts (print):	108:21407

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