Sciact
  • EN
  • RU

Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate Научная публикация

Журнал Inorganics
, E-ISSN: 2304-6740
Вых. Данные Год: 2022, Том: 10, Номер: 2, Номер статьи : 15, Страниц : 10 DOI: 10.3390/inorganics10020015
Ключевые слова melting-assisted solvent-free synthesis; copper complex; imidazole; nanoparticles
Авторы Netskina Olga V. 1 , Mukha Svetlana A. 1 , Dmitruk Kirill A. 1 , Ishchenko Arkady V. 1 , Bulavchenko Olga A. 1 , Pochtar Alena A. 1 , Suknev Alexey P. 1 , Komova Oxana V. 1,2
Организации
1 Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2 Siberian Branch of Russian Academy of Sciences, Pr. Akademika Lavrentieva 17, 630090 Novosibirsk, Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 075-15-2020-781

Реферат: The development of solvent-free techniques for nanoparticles synthesis is one of the challenges of Green chemistry. In this work, the principled opportunity to obtain copper-containing nanosized particles without use of any solvents was shown. The copper complexes were prepared as precursors by the melting-assisted solvent-free synthesis. The formation of tetra(imidazole)copper(II) nitrate complex was confirmed by XRD, elemental analysis, FTIR spectroscopy, and thermal analysis. It was noted that their thermal decomposition occurs in two stages: (I) the low-temperature step may be related to redox interaction between organic ligands and nitrate-anions; (II) the high-temperature step may be related to the oxidation of the products of incomplete imidazole decomposition. TEM and XRD studies of solid products of complex combustion have shown that they are oxides with particle size less than 40 nm. Thus, the combustion of [Cu(Im)4](NO3)2 complex under air can be considered as a new approach to prepare nanosized particles of copper oxides without the use of solvents
Библиографическая ссылка: Netskina O.V. , Mukha S.A. , Dmitruk K.A. , Ishchenko A.V. , Bulavchenko O.A. , Pochtar A.A. , Suknev A.P. , Komova O.V.
Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate
Inorganics. 2022. V.10. N2. 15 :1-10. DOI: 10.3390/inorganics10020015 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 20 дек. 2021 г.
Принята к публикации: 19 янв. 2022 г.
Опубликована online: 21 янв. 2022 г.
Опубликована в печати: 1 февр. 2022 г.
Идентификаторы БД:
Web of science: WOS:000763448200001
Scopus: 2-s2.0-85123689321
РИНЦ: 48146573
Chemical Abstracts: 2022:591810
OpenAlex: W4206786452
Цитирование в БД:
БД Цитирований
Scopus 3
Web of science 3
РИНЦ 2
OpenAlex 3
Альметрики: