Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate Full article
| Journal |
Inorganics
, E-ISSN: 2304-6740 |
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| Output data | Year: 2022, Volume: 10, Number: 2, Article number : 15, Pages count : 10 DOI: 10.3390/inorganics10020015 | ||||
| Tags | melting-assisted solvent-free synthesis; copper complex; imidazole; nanoparticles | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 075-15-2020-781 |
Abstract:
The development of solvent-free techniques for nanoparticles synthesis is one of the challenges of Green chemistry. In this work, the principled opportunity to obtain copper-containing nanosized particles without use of any solvents was shown. The copper complexes were prepared as precursors by the melting-assisted solvent-free synthesis. The formation of tetra(imidazole)copper(II) nitrate complex was confirmed by XRD, elemental analysis, FTIR spectroscopy, and thermal analysis. It was noted that their thermal decomposition occurs in two stages: (I) the low-temperature step may be related to redox interaction between organic ligands and nitrate-anions; (II) the high-temperature step may be related to the oxidation of the products of incomplete imidazole decomposition. TEM and XRD studies of solid products of complex combustion have shown that they are oxides with particle size less than 40 nm. Thus, the combustion of [Cu(Im)4](NO3)2 complex under air can be considered as a new approach to prepare nanosized particles of copper oxides without the use of solvents
Cite:
Netskina O.V.
, Mukha S.A.
, Dmitruk K.A.
, Ishchenko A.V.
, Bulavchenko O.A.
, Pochtar A.A.
, Suknev A.P.
, Komova O.V.
Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate
Inorganics. 2022. V.10. N2. 15 :1-10. DOI: 10.3390/inorganics10020015 WOS Scopus РИНЦ AN OpenAlex
Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate
Inorganics. 2022. V.10. N2. 15 :1-10. DOI: 10.3390/inorganics10020015 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Dec 20, 2021 |
| Accepted: | Jan 19, 2022 |
| Published online: | Jan 21, 2022 |
| Published print: | Feb 1, 2022 |
Identifiers:
| Web of science: | WOS:000763448200001 |
| Scopus: | 2-s2.0-85123689321 |
| Elibrary: | 48146573 |
| Chemical Abstracts: | 2022:591810 |
| OpenAlex: | W4206786452 |