The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts | Sciact - CRIS-система Института катализа

The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts Научная публикация

Журнал

Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X

Вых. Данные

Год: 2020, Том: 58, Номер: 1, Страницы: 84-96 Страниц : 13 DOI: 10.1002/mrc.4931

Ключевые слова

1H and 13C NMR spectroscopy, aqueous‐phase reaction, catalytic hydrogenation, palladium catalyst, trinitrobenzoic acid

Авторы

Talsi Valentin P. ¹ , Belskaya Olga B. ^1,2 , Yurpalov Vyacheslav L. ¹

Организации

1	Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Omsk, Russia
2	Department of Chemical Technology, Omsk State Technical University, Omsk, Russia

Due to a detailed analysis of NMR spectra of the reaction solutions with different composition obtained by the aqueous-phase catalytic (Pd/C) hydrogenation of 2,4,6-trinitrobenzoic acid, the intermediate compounds were identified and a more substantiated mechanism was proposed for the formation of the main reaction products—1,3,5-triaminobenzene and cyclohexane-1,3,5-trione trioxime. The condensation of the 1,3,5-triaminobenzene molecules produced by a complete hydrogenation of 2,4,6-trinitrobenzoic acid was shown to result in the formation of a paramagnetic heterocyclic compound.

Talsi V.P. , Belskaya O.B. , Yurpalov V.L.
The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex ЦНХТ ID

Поступила в редакцию:	8 мая 2019 г.
Принята к публикации:	24 июл. 2019 г.
Опубликована online:	30 июл. 2019 г.
Опубликована в печати:	1 янв. 2020 г.

Web of science:	WOS:000481454200001
Scopus:	2-s2.0-85070747661
РИНЦ:	43207006
Chemical Abstracts:	2019:1595445
Chemical Abstracts (print):	172:67666
PMID (PubMed):	31361050
OpenAlex:	W2966063862
ЦНХТ ID:	1862

БД	Цитирований
Scopus	4
OpenAlex	8
РИНЦ	4
Web of science	5