The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts Full article
| Journal |
Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X |
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| Output data | Year: 2020, Volume: 58, Number: 1, Pages: 84-96 Pages count : 13 DOI: 10.1002/mrc.4931 | ||||
| Tags | 1H and 13C NMR spectroscopy, aqueous‐phase reaction, catalytic hydrogenation, palladium catalyst, trinitrobenzoic acid | ||||
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Abstract:
Due to a detailed analysis of NMR spectra of the reaction solutions with different composition obtained by the aqueous-phase catalytic (Pd/C) hydrogenation of 2,4,6-trinitrobenzoic acid, the intermediate compounds were identified and a more substantiated mechanism was proposed for the formation of the main reaction products—1,3,5-triaminobenzene and cyclohexane-1,3,5-trione trioxime. The condensation of the 1,3,5-triaminobenzene molecules produced by a complete hydrogenation of 2,4,6-trinitrobenzoic acid was shown to result in the formation of a paramagnetic heterocyclic compound.
Cite:
Talsi V.P.
, Belskaya O.B.
, Yurpalov V.L.
The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ ANCAN PMID OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C catalysts
Magnetic Resonance in Chemistry. 2020. V.58. N1. P.84-96. DOI: 10.1002/mrc.4931 WOS Scopus РИНЦ ANCAN PMID OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | May 8, 2019 |
| Accepted: | Jul 24, 2019 |
| Published online: | Jul 30, 2019 |
| Published print: | Jan 1, 2020 |
Identifiers:
| Web of science: | WOS:000481454200001 |
| Scopus: | 2-s2.0-85070747661 |
| Elibrary: | 43207006 |
| Chemical Abstracts: | 2019:1595445 |
| Chemical Abstracts (print): | 172:67666 |
| PMID: | 31361050 |
| OpenAlex: | W2966063862 |
| publication_identifier.sciact_ihcp_identifier_type: | 1862 |