Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State | Sciact - CRIS-система Института катализа

Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State Научная публикация

Журнал

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Вых. Данные

Год: 2012, Том: 48, Страницы: 9266-9268 Страниц : 3 DOI: 10.1039/c2cc34577c

Ключевые слова

CATALYSIS; H2O2

Авторы

Jimenez-Lozano Pablo ¹ , Ivanchikova Irina D. ² , Kholdeeva Oxana A. ² , Poblet Josep M. ¹ , Carbó Jorge J. ¹

Организации

1	Departament de Quı´mica Fı´sica i Inorga`nica, Universitat Rovira i Virgili, Campus Sescelades, C/Marcel.lı´ Domingo s/n, 43007 Tarragona, Spain
2	Boreskov Institute of Catalysis, Lavrentiev av. 5, Novosibirsk 630090, Russia

Информация о финансировании (3)

1	Ministry of Economic Affairs and Digital Transformation	CTQ2011-29054-C02-01
2	Government of Catalonia	2009SGR462
3	Government of Catalonia	XRQTC

Kinetic and DFT studies revealed that protonation of Ti-containing polyoxometalates (Ti-POM) lowers significantly the energy barrier for the heterolytic oxygen transfer from the Ti hydroperoxo intermediate to the alkene, increasing the activity and selectivity of alkene oxidation.

Jimenez-Lozano P. , Ivanchikova I.D. , Kholdeeva O.A. , Poblet J.M. , Carbó J.J.
Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State
Chemical Communications. 2012. V.48. P.9266-9268. DOI: 10.1039/c2cc34577c WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	26 июн. 2012 г.
Принята к публикации:	25 июл. 2012 г.
Опубликована online:	10 авг. 2012 г.
Опубликована в печати:	20 авг. 2012 г.

Web of science:	WOS:000307646700015
Scopus:	2-s2.0-84865209987
РИНЦ:	20495882
Chemical Abstracts:	2012:1220125
Chemical Abstracts (print):	157:465069
OpenAlex:	W2061967900

БД	Цитирований
Web of science	44
Scopus	47
РИНЦ	41
OpenAlex	48