Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State Научная публикация
| Журнал |
Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X |
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| Вых. Данные | Год: 2012, Том: 48, Страницы: 9266-9268 Страниц : 3 DOI: 10.1039/c2cc34577c | ||||
| Ключевые слова | CATALYSIS; H2O2 | ||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Ministry of Economic Affairs and Digital Transformation | CTQ2011-29054-C02-01 |
| 2 | Government of Catalonia | 2009SGR462 |
| 3 | Government of Catalonia | XRQTC |
Реферат:
Kinetic and DFT studies revealed that protonation of Ti-containing polyoxometalates (Ti-POM) lowers significantly the energy barrier for the heterolytic oxygen transfer from the Ti hydroperoxo intermediate to the alkene, increasing the activity and selectivity of alkene oxidation.
Библиографическая ссылка:
Jimenez-Lozano P.
, Ivanchikova I.D.
, Kholdeeva O.A.
, Poblet J.M.
, Carbó J.J.
Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State
Chemical Communications. 2012. V.48. P.9266-9268. DOI: 10.1039/c2cc34577c WOS Scopus РИНЦ CAPlusCA OpenAlex
Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State
Chemical Communications. 2012. V.48. P.9266-9268. DOI: 10.1039/c2cc34577c WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 26 июн. 2012 г. |
| Принята к публикации: | 25 июл. 2012 г. |
| Опубликована online: | 10 авг. 2012 г. |
| Опубликована в печати: | 20 авг. 2012 г. |
Идентификаторы БД:
| Web of science: | WOS:000307646700015 |
| Scopus: | 2-s2.0-84865209987 |
| РИНЦ: | 20495882 |
| Chemical Abstracts: | 2012:1220125 |
| Chemical Abstracts (print): | 157:465069 |
| OpenAlex: | W2061967900 |