Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State | Sciact - CRIS-system of Boreskov Institute of Catalysis

Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2012, Volume: 48, Pages: 9266-9268 Pages count : 3 DOI: 10.1039/c2cc34577c

Tags

CATALYSIS; H2O2

Authors

Jimenez-Lozano Pablo ¹ , Ivanchikova Irina D. ² , Kholdeeva Oxana A. ² , Poblet Josep M. ¹ , Carbó Jorge J. ¹

Affiliations

1	Departament de Quı´mica Fı´sica i Inorga`nica, Universitat Rovira i Virgili, Campus Sescelades, C/Marcel.lı´ Domingo s/n, 43007 Tarragona, Spain
2	Boreskov Institute of Catalysis, Lavrentiev av. 5, Novosibirsk 630090, Russia

Funding (3)

1	Ministry of Economic Affairs and Digital Transformation	CTQ2011-29054-C02-01
2	Government of Catalonia	2009SGR462
3	Government of Catalonia	XRQTC

Kinetic and DFT studies revealed that protonation of Ti-containing polyoxometalates (Ti-POM) lowers significantly the energy barrier for the heterolytic oxygen transfer from the Ti hydroperoxo intermediate to the alkene, increasing the activity and selectivity of alkene oxidation.

Jimenez-Lozano P. , Ivanchikova I.D. , Kholdeeva O.A. , Poblet J.M. , Carbó J.J.
Alkene Oxidation by Ti-Containing Polyoxometalates. Unambiguous Characterization of the Role of the Protonation State
Chemical Communications. 2012. V.48. P.9266-9268. DOI: 10.1039/c2cc34577c WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jun 26, 2012
Accepted:	Jul 25, 2012
Published online:	Aug 10, 2012
Published print:	Aug 20, 2012

Web of science:	WOS:000307646700015
Scopus:	2-s2.0-84865209987
Elibrary:	20495882
Chemical Abstracts:	2012:1220125
Chemical Abstracts (print):	157:465069
OpenAlex:	W2061967900

DB	Citing
Web of science	44
Scopus	47
Elibrary	42
OpenAlex	50