Two-Component Pd-Containing Composites Based on Aerogel-Prepared MgO for Catalytic Dehydrogenation of Ethane ArticleGenre_short.SHORT_COMMUNICATION
| Journal |
Journal of Sol-Gel Science and Technology
ISSN: 0928-0707 , E-ISSN: 1573-4846 |
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| Output data | Year: 2023, Volume: 105, Pages: 315–323 Pages count : 9 DOI: 10.1007/s10971-022-05999-3 | ||
| Tags | Sol-gel synthesis; aerogels; composite catalytic system; palladium; MgO; ethane dehydrogenation | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0010 |
Abstract:
MgO-based aerogel composites are attractive as heterogeneous catalysts. The present research is aimed to develop an efficient system for olefins production via dehydrogenation of corresponding alkanes. In order to improve the yield of target olefin, an approach considering the uptake of released hydrogen by so-called oxygen carrier systems was utilized. Thus, the composite systems consisting of the Pd-Mg-O component, responsible for the dehydrogenation stage, and M-Mg-O (M = Ni, Cu, Fe) component, serving as an oxygen carrier, were prepared and characterized. The reproducibility of the samples towards the hydrogen uptake in consecutive redox cycles was studied by the temperature-programmed reduction method. The efficacy of the composites was compared in a model reaction of ethane dehydrogenation.
Cite:
Veselov G.B.
, Ilyina E.V.
, Vedyagin A.A.
Two-Component Pd-Containing Composites Based on Aerogel-Prepared MgO for Catalytic Dehydrogenation of Ethane
Journal of Sol-Gel Science and Technology. 2023. V.105. P.315–323. DOI: 10.1007/s10971-022-05999-3 WOS Scopus РИНЦ ANCAN OpenAlex
Two-Component Pd-Containing Composites Based on Aerogel-Prepared MgO for Catalytic Dehydrogenation of Ethane
Journal of Sol-Gel Science and Technology. 2023. V.105. P.315–323. DOI: 10.1007/s10971-022-05999-3 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 8, 2022 |
| Accepted: | Nov 14, 2022 |
| Published online: | Dec 20, 2022 |
| Published print: | Feb 10, 2023 |
Identifiers:
| Web of science: | WOS:000899350600001 |
| Scopus: | 2-s2.0-85144290845 |
| Elibrary: | 54017120 |
| Chemical Abstracts: | 2022:3151218 |
| Chemical Abstracts (print): | 181:358144 |
| OpenAlex: | W4311924823 |