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Porous Hollow Nanostructure Promoting the Catalytic Performance and Stability of Ni3P in Furfural Hydrogenation Научная публикация

Журнал Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045
Вых. Данные Год: 2023, Том: 62, Номер: 8, Страницы: 3525–3537 Страниц : 13 DOI: 10.1021/acs.iecr.2c03327
Ключевые слова Aldehydes; Catalyst selectivity; Furfural; Nickel compounds; Phase separation; Phosphorus compounds
Авторы Sun Ruyu 1 , Tian Ye 1 , Xiao Linfei 1 , Bukhtiyarova Galina A. 2 , Wu Wei 1
Организации
1 National Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, P. R. China
2 Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Ministry of Science and Technology of the People's Republic of China 2018YFE0108800

Реферат: In the processes of hydrogenation, the accurate control of product distribution is crucial to the high-value conversion of furfural. Herein, Ni3P catalysts were prepared by phase separation synthesis with porous hollow nanospheres and employed as catalysts for the hydrogenation of furfural. Over the Ni3P-400 catalyst, furfural could be transformed completely with 95.6% selectivity toward furfuryl alcohol under 120 °C and 1.6 MPa for 4 h. The deactivation of the Ni3P-400 catalyst was not observed during 8-run recycling tests. Moreover, using other carbonyl compounds derived from biomass as substrates, excellent catalytic performance was also obtained. Such exceptional features make the Ni3P-400 catalyst promising for industrial applications not only in hydrogenation of furfural but also in hydrogenation of other carbonyl substrates.
Библиографическая ссылка: Sun R. , Tian Y. , Xiao L. , Bukhtiyarova G.A. , Wu W.
Porous Hollow Nanostructure Promoting the Catalytic Performance and Stability of Ni3P in Furfural Hydrogenation
Industrial and Engineering Chemistry Research. 2023. V.62. N8. P.3525–3537. DOI: 10.1021/acs.iecr.2c03327 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 26 сент. 2022 г.
Принята к публикации: 8 февр. 2023 г.
Опубликована online: 19 февр. 2023 г.
Опубликована в печати: 1 мар. 2023 г.
Идентификаторы БД:
Web of science: WOS:000937967800001
Scopus: 2-s2.0-85148510457
РИНЦ: 54175607
Chemical Abstracts: 2023:337171
Chemical Abstracts (print): 182:11432
OpenAlex: W4321374308
Цитирование в БД:
БД Цитирований
Scopus 3
Web of science 2
OpenAlex 3
РИНЦ 3
Альметрики: