Porous Hollow Nanostructure Promoting the Catalytic Performance and Stability of Ni3P in Furfural Hydrogenation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Porous Hollow Nanostructure Promoting the Catalytic Performance and Stability of Ni3P in Furfural Hydrogenation Full article

Journal

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Output data

Year: 2023, Volume: 62, Number: 8, Pages: 3525–3537 Pages count : 13 DOI: 10.1021/acs.iecr.2c03327

Tags

Aldehydes; Catalyst selectivity; Furfural; Nickel compounds; Phase separation; Phosphorus compounds

Authors

Sun Ruyu ¹ , Tian Ye ¹ , Xiao Linfei ¹ , Bukhtiyarova Galina A. ² , Wu Wei ¹

Affiliations

1	National Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, P. R. China
2	Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia

Funding (1)

Ministry of Science and Technology of the People's Republic of China

2018YFE0108800

In the processes of hydrogenation, the accurate control of product distribution is crucial to the high-value conversion of furfural. Herein, Ni3P catalysts were prepared by phase separation synthesis with porous hollow nanospheres and employed as catalysts for the hydrogenation of furfural. Over the Ni3P-400 catalyst, furfural could be transformed completely with 95.6% selectivity toward furfuryl alcohol under 120 °C and 1.6 MPa for 4 h. The deactivation of the Ni3P-400 catalyst was not observed during 8-run recycling tests. Moreover, using other carbonyl compounds derived from biomass as substrates, excellent catalytic performance was also obtained. Such exceptional features make the Ni3P-400 catalyst promising for industrial applications not only in hydrogenation of furfural but also in hydrogenation of other carbonyl substrates.

Sun R. , Tian Y. , Xiao L. , Bukhtiyarova G.A. , Wu W.
Porous Hollow Nanostructure Promoting the Catalytic Performance and Stability of Ni3P in Furfural Hydrogenation
Industrial and Engineering Chemistry Research. 2023. V.62. N8. P.3525–3537. DOI: 10.1021/acs.iecr.2c03327 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Sep 26, 2022
Accepted:	Feb 8, 2023
Published online:	Feb 19, 2023
Published print:	Mar 1, 2023

Web of science:	WOS:000937967800001
Scopus:	2-s2.0-85148510457
Elibrary:	54175607
Chemical Abstracts:	2023:337171
Chemical Abstracts (print):	182:11432
OpenAlex:	W4321374308

DB	Citing
Scopus	5
Web of science	3
OpenAlex	5
Elibrary	3