Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2022, Том: 63, Номер: 6, Страницы: 645–652 Страниц : 8 DOI: 10.1134/S0023158422060040 | ||
| Ключевые слова | catalysis, effect of reaction medium, activation energy, Brønsted coefficients | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0014 |
Реферат:
The thermodynamics of the catalytic cycle under the influence of the reaction medium on the catalyst was considered. The change in the activation energy of the reaction depending on the change in the heat of the reaction step was described by the Brønsted–Evans–Polanyi relation. For the two-step scheme of the catalytic reaction (nonlinear Eley–Rideal mechanism), the relationship between the Brønsted coefficients of the steps of the catalytic reaction was shown. For the three-step scheme of the catalytic reaction (nonlinear Langmuir–Hinshelwood mechanism), a balance equation containing the Brønsted coefficients and the increments of the heats of the steps of the catalytic reaction was obtained, based on which some particular cases were analyzed.
Библиографическая ссылка:
Gerasev A.P.
Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction
Kinetics and Catalysis. 2022. V.63. N6. P.645–652. DOI: 10.1134/S0023158422060040 WOS Scopus РИНЦ CAPlus OpenAlex
Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction
Kinetics and Catalysis. 2022. V.63. N6. P.645–652. DOI: 10.1134/S0023158422060040 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная:
Герасев А.П.
Соотношение между коэффициентами Бренстеда стадий гетерогенных каталитических реакций
Кинетика и катализ. 2022. Т.63. №6. С.727-735. DOI: 10.31857/S0453881122060041 РИНЦ OpenAlex
Соотношение между коэффициентами Бренстеда стадий гетерогенных каталитических реакций
Кинетика и катализ. 2022. Т.63. №6. С.727-735. DOI: 10.31857/S0453881122060041 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 8 апр. 2022 г. |
| Принята к публикации: | 20 июл. 2022 г. |
| Опубликована в печати: | 1 дек. 2022 г. |
| Опубликована online: | 6 мар. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:000944025100003 |
| Scopus: | 2-s2.0-85149406307 |
| РИНЦ: | 50437911 |
| Chemical Abstracts: | 2023:464325 |
| OpenAlex: | W4323339414 |
Цитирование в БД:
Пока нет цитирований