Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2022, Volume: 63, Number: 6, Pages: 645–652 Pages count : 8 DOI: 10.1134/S0023158422060040

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

0239-2021-0014

The thermodynamics of the catalytic cycle under the influence of the reaction medium on the catalyst was considered. The change in the activation energy of the reaction depending on the change in the heat of the reaction step was described by the Brønsted–Evans–Polanyi relation. For the two-step scheme of the catalytic reaction (nonlinear Eley–Rideal mechanism), the relationship between the Brønsted coefficients of the steps of the catalytic reaction was shown. For the three-step scheme of the catalytic reaction (nonlinear Langmuir–Hinshelwood mechanism), a balance equation containing the Brønsted coefficients and the increments of the heats of the steps of the catalytic reaction was obtained, based on which some particular cases were analyzed.

Gerasev A.P.
Relationship between the Brønsted Coefficients of the Steps of a Heterogeneous Catalytic Reaction
Kinetics and Catalysis. 2022. V.63. N6. P.645–652. DOI: 10.1134/S0023158422060040 WOS Scopus РИНЦ AN OpenAlex

Герасев А.П.
Соотношение между коэффициентами Бренстеда стадий гетерогенных каталитических реакций
Кинетика и катализ. 2022. Т.63. №6. С.727-735. DOI: 10.31857/S0453881122060041 РИНЦ OpenAlex

Submitted:	Apr 8, 2022
Accepted:	Jul 20, 2022
Published print:	Dec 1, 2022
Published online:	Mar 6, 2023

Web of science:	WOS:000944025100003
Scopus:	2-s2.0-85149406307
Elibrary:	50437911
Chemical Abstracts:	2023:464325
OpenAlex:	W4323339414

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