Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters Научная публикация
| Журнал |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Вых. Данные | Год: 2015, Том: 163, Страницы: 531-538 Страниц : 8 DOI: 10.1016/j.apcatb.2014.08.001 | ||||||
| Ключевые слова | Biofuel, Hydrocarbon, Hydrodeoxygenation, Ni-based catalysts | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Российский фонд фундаментальных исследований | 14-03-31844 |
| 2 | Министерство образования и науки Российской Федерации | |
| 3 | Фонд «Сколково» | 64 от 02.07.2012г. |
Реферат:
The effect of molybdenum on activity of Ni-based catalysts in the hydrodeoxygenation of fatty acid esters was studied. Catalysts Ni-Cu/Al2O3, Ni-Mo/Al2O3, Cu-Mo/Al2O3, Mo/Al2O3, and Ni-Cu-Mo/Al2O3 with different ratios Ni/Mo were prepared and tested in the hydrodeoxygenation of methyl palmitate and ethyl caprate at 300 °С, 1 MPa. It was found that an increase in the Mo content (from 0.0% to 6.9%) in the Ni-Cu-Mo/Al2O3 catalysts leads to an increase in the yield of normal alkanes. The catalysts were characterized by X-ray photoelectron spectroscopy (XPS), temperature programmed reduction and X-ray diffraction techniques. The XPS data showed that the increase in the conversion of fatty acid esters is related to changes in the ratio between different oxidation states of molybdenum (Mo0, Mo4+, and Mo6+) on the surface of the Ni-Cu-Mo/Al2O3 catalysts.
Библиографическая ссылка:
Kukushkin R.G.
, Bulavchenko O.A.
, Kaichev V.V.
, Yakovlev V.A.
Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters
Applied Catalysis B: Environmental. 2015. V.163. P.531-538. DOI: 10.1016/j.apcatb.2014.08.001 WOS Scopus РИНЦ CAPlusCA OpenAlex
Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters
Applied Catalysis B: Environmental. 2015. V.163. P.531-538. DOI: 10.1016/j.apcatb.2014.08.001 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 19 мая 2014 г. |
| Принята к публикации: | 2 авг. 2014 г. |
| Опубликована online: | 11 авг. 2014 г. |
| Опубликована в печати: | 1 февр. 2015 г. |
Идентификаторы БД:
| Web of science: | WOS:000343612500058 |
| Scopus: | 2-s2.0-84908626478 |
| РИНЦ: | 23956810 |
| Chemical Abstracts: | 2014:1376629 |
| Chemical Abstracts (print): | 161:537317 |
| OpenAlex: | W2071107872 |