Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters Full article
| Journal |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Output data | Year: 2015, Volume: 163, Pages: 531-538 Pages count : 8 DOI: 10.1016/j.apcatb.2014.08.001 | ||||||
| Tags | Biofuel, Hydrocarbon, Hydrodeoxygenation, Ni-based catalysts | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 14-03-31844 |
| 2 | The Ministry of Education and Science of the Russian Federation | |
| 3 | Skolkovo Foundation | 64 от 02.07.2012г. |
Abstract:
The effect of molybdenum on activity of Ni-based catalysts in the hydrodeoxygenation of fatty acid esters was studied. Catalysts Ni-Cu/Al2O3, Ni-Mo/Al2O3, Cu-Mo/Al2O3, Mo/Al2O3, and Ni-Cu-Mo/Al2O3 with different ratios Ni/Mo were prepared and tested in the hydrodeoxygenation of methyl palmitate and ethyl caprate at 300 °С, 1 MPa. It was found that an increase in the Mo content (from 0.0% to 6.9%) in the Ni-Cu-Mo/Al2O3 catalysts leads to an increase in the yield of normal alkanes. The catalysts were characterized by X-ray photoelectron spectroscopy (XPS), temperature programmed reduction and X-ray diffraction techniques. The XPS data showed that the increase in the conversion of fatty acid esters is related to changes in the ratio between different oxidation states of molybdenum (Mo0, Mo4+, and Mo6+) on the surface of the Ni-Cu-Mo/Al2O3 catalysts.
Cite:
Kukushkin R.G.
, Bulavchenko O.A.
, Kaichev V.V.
, Yakovlev V.A.
Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters
Applied Catalysis B: Environmental. 2015. V.163. P.531-538. DOI: 10.1016/j.apcatb.2014.08.001 WOS Scopus РИНЦ ANCAN OpenAlex
Influence of Mo on Catalytic Activity of Ni-Based Catalysts in Hydrodeoxygenation of Esters
Applied Catalysis B: Environmental. 2015. V.163. P.531-538. DOI: 10.1016/j.apcatb.2014.08.001 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 19, 2014 |
| Accepted: | Aug 2, 2014 |
| Published online: | Aug 11, 2014 |
| Published print: | Feb 1, 2015 |
Identifiers:
| Web of science: | WOS:000343612500058 |
| Scopus: | 2-s2.0-84908626478 |
| Elibrary: | 23956810 |
| Chemical Abstracts: | 2014:1376629 |
| Chemical Abstracts (print): | 161:537317 |
| OpenAlex: | W2071107872 |