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Composition and Optical Properties of Amorphous Plasma-Chemical Silicon Oxynitride of Variable Composition α-SiOxNy : H Научная публикация

Журнал Technical Physics
ISSN: 1063-7842 , E-ISSN: 1090-6525
Вых. Данные Год: 2023, Том: 68, Номер: 4, Страницы: 538-545 Страниц : 8 DOI: 10.21883/tp.2023.04.55947.167-22
Ключевые слова silicon oxynitride, plasma-chemical deposition, stoichiometric composition, Si nanoclusters
Авторы Volodin V.A. 1,2 , Kamaev G.N. 1 , Gritsenko V.A. 1,3 , Chepkova S.G. 1 , Prosvirin I.P. 4
Организации
1 Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2 Novosibirsk State University, Novosibirsk, Russia
3 Novosibirsk State Technical University, Novosibirsk, Russia
4 Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, Russia

Информация о финансировании (1)

1 Российский научный фонд 22-19-00369

Реферат: The α-SiOxNy : H films of various compositions were obtained by plasma chemical deposition from a gas mixture of 10% monosilane (diluted with argon) and nitrogen in the presence of residual oxygen in the working gas mixture. The nitrogen flow rate varied in the range from 4 to 6 cm3/min, the power of the high-frequency generator (13.56 MHz) varied in the range of 50-150 Watts. The electronic structure and optical properties of the films were studied using X-ray photoelectron spectroscopy, vibrational spectroscopy, transmission and reflection spectroscopy, and spectral ellipsometry. It is shown that, as the generator power decreases, the content of excess silicon in the films increases and amorphous silicon nanoclusters appear. As the generator power increases, the oxygen concentration in the films decreases. Apparently, this is due to the greater dissociation of molecular nitrogen with an increase in the power of the plasma discharge and an increase in the concentration of active nitrogen. Thus, it is possible to control the composition of aα-SiOxNy : H films not only by changing the nitrogen flow, but also by varying the generator power.
Библиографическая ссылка: Volodin V.A. , Kamaev G.N. , Gritsenko V.A. , Chepkova S.G. , Prosvirin I.P.
Composition and Optical Properties of Amorphous Plasma-Chemical Silicon Oxynitride of Variable Composition α-SiOxNy : H
Technical Physics. 2023. V.68. N4. P.538-545. DOI: 10.21883/tp.2023.04.55947.167-22 РИНЦ OpenAlex
Оригинальная: Володин В.А. , Камаев Г.Н. , Гриценко В.А. , Черкова С.Г. , Просвирин И.П.
Состав и оптические свойства аморфного плазмохимического оксинитрида кремния переменного состава a-SiOxNy : H
Журнал технической физики. 2023. Т.93. №4. С.575-582. DOI: 10.21883/jtf.2023.04.55047.167-22 РИНЦ OpenAlex
Даты:
Поступила в редакцию: 23 июн. 2022 г.
Принята к публикации: 2 февр. 2023 г.
Идентификаторы БД:
РИНЦ: 59428287
OpenAlex: W4385249221
Цитирование в БД: Пока нет цитирований
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