Сatalysts for Electrooxidation of Biomass Processing Products Обзор
| Журнал |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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| Вых. Данные | Год: 2023, Том: 96, Номер: 2, Страницы: 123-142 Страниц : 20 DOI: 10.1134/s1070427223020016 | ||
| Ключевые слова | electrocatalysis, biomass processing, glycerol, glucose, 5-hydroxymethylfurfural, furfural | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | ГЗ-2021-2023 |
Реферат:
In recent years, active research has been carried out in the field of catalysts for the electrooxidation of water-soluble products of biomass processing on the anodes of electrolysers, coupled with the process of producing hydrogen at the cathodes of these devices. Biomass processing products that are promising for electrooxidation are glycerol, glucose, furfural and 5-hydroxymethylfurfural. The review examines studies of catalysts for the electrooxidation of glycerol, glucose, furfural, and 5-hydroxymethylfurfural based on metals of various groups. Electrooxidation of these organic compounds on catalysts based on noble metals (platinum group metals and gold) and their alloys begins in the potential range from 0.3 to 0.7 V [reversible hydrogen electrode (RHE)], reaching a maximum at ~1 V (RHE). The main disadvantage of catalysts based on noble metals is their high cost. Nickel and сobalt are considered promising among the non-noble metals studied as components of catalysts for these reactions. But in the presence of catalysts based on these metals, the electrooxidation reactions of the noted organic compounds begin at potentials above 1 V (RHE). Glyceraldehyde, dihydroxyacetone, glyceric, tartronic, glycolic, oxalic, glyoxalic and mesoxalic acids can be obtained from the electrooxidation of glycerol. Valuable products of the electrooxidation of glucose, furfural, and 5-hydroxymethylfurfural are gluconic, 2-furancarboxylic, and 2,5-furandicarboxylic acids, respectively.
Библиографическая ссылка:
Sherstyuk O.V.
, Kuznetsov A.N.
, Kozlov D.V.
Сatalysts for Electrooxidation of Biomass Processing Products
Russian Journal of Applied Chemistry. 2023. V.96. N2. P.123-142. DOI: 10.1134/s1070427223020016 WOS Scopus РИНЦ CAPlus OpenAlex
Сatalysts for Electrooxidation of Biomass Processing Products
Russian Journal of Applied Chemistry. 2023. V.96. N2. P.123-142. DOI: 10.1134/s1070427223020016 WOS Scopus РИНЦ CAPlus OpenAlex
Оригинальная:
Шерстюк О.В.
, Кузнецов А.Н.
, Козлов Д.В.
Катализаторы процессов электроокисления продуктов переработки биомассы (обзор)
Журнал прикладной химии. 2023. Т.96. №2. С.123-146. DOI: 10.31857/S0044461823020019 РИНЦ OpenAlex
Катализаторы процессов электроокисления продуктов переработки биомассы (обзор)
Журнал прикладной химии. 2023. Т.96. №2. С.123-146. DOI: 10.31857/S0044461823020019 РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 февр. 2023 г. |
| Поступила в редакцию: | 21 июл. 2023 г. |
| Принята к публикации: | 5 сент. 2023 г. |
| Опубликована online: | 13 дек. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001123684900013 |
| Scopus: | 2-s2.0-85179656160 |
| РИНЦ: | 56643804 |
| Chemical Abstracts: | 2023:2635978 |
| OpenAlex: | W4389671753 |
Цитирование в БД:
Пока нет цитирований