Sciact
  • EN
  • RU

Сatalysts for Electrooxidation of Biomass Processing Products Review

Journal Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Output data Year: 2023, Volume: 96, Number: 2, Pages: 123-142 Pages count : 20 DOI: 10.1134/s1070427223020016
Tags electrocatalysis, biomass processing, glycerol, glucose, 5-hydroxymethylfurfural, furfural
Authors Sherstyuk O.V. 1 , Kuznetsov A.N. 1 , Kozlov D.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation ГЗ-2021-2023

Abstract: In recent years, active research has been carried out in the field of catalysts for the electrooxidation of water-soluble products of biomass processing on the anodes of electrolysers, coupled with the process of producing hydrogen at the cathodes of these devices. Biomass processing products that are promising for electrooxidation are glycerol, glucose, furfural and 5-hydroxymethylfurfural. The review examines studies of catalysts for the electrooxidation of glycerol, glucose, furfural, and 5-hydroxymethylfurfural based on metals of various groups. Electrooxidation of these organic compounds on catalysts based on noble metals (platinum group metals and gold) and their alloys begins in the potential range from 0.3 to 0.7 V [reversible hydrogen electrode (RHE)], reaching a maximum at ~1 V (RHE). The main disadvantage of catalysts based on noble metals is their high cost. Nickel and сobalt are considered promising among the non-noble metals studied as components of catalysts for these reactions. But in the presence of catalysts based on these metals, the electrooxidation reactions of the noted organic compounds begin at potentials above 1 V (RHE). Glyceraldehyde, dihydroxyacetone, glyceric, tartronic, glycolic, oxalic, glyoxalic and mesoxalic acids can be obtained from the electrooxidation of glycerol. Valuable products of the electrooxidation of glucose, furfural, and 5-hydroxymethylfurfural are gluconic, 2-furancarboxylic, and 2,5-furandicarboxylic acids, respectively.
Cite: Sherstyuk O.V. , Kuznetsov A.N. , Kozlov D.V.
Сatalysts for Electrooxidation of Biomass Processing Products
Russian Journal of Applied Chemistry. 2023. V.96. N2. P.123-142. DOI: 10.1134/s1070427223020016 WOS Scopus РИНЦ AN OpenAlex
Original: Шерстюк О.В. , Кузнецов А.Н. , Козлов Д.В.
Катализаторы процессов электроокисления продуктов переработки биомассы (обзор)
Журнал прикладной химии. 2023. Т.96. №2. С.123-146. DOI: 10.31857/S0044461823020019 РИНЦ OpenAlex
Dates:
Published print: Feb 1, 2023
Submitted: Jul 21, 2023
Accepted: Sep 5, 2023
Published online: Dec 13, 2023
Identifiers:
Web of science: WOS:001123684900013
Scopus: 2-s2.0-85179656160
Elibrary: 56643804
Chemical Abstracts: 2023:2635978
OpenAlex: W4389671753
Citing: Пока нет цитирований
Altmetrics: