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Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions Научная публикация

Журнал Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Вых. Данные Год: 2019, Том: 92, Номер: 10, Страницы: 1383-1391 Страниц : 9 DOI: 10.1134/S1070427219100082
Ключевые слова mixed oxide, catalytic cracking, vegetable oil, hydrogen-transfer reactions
Авторы Lipin P.V. 1 , Potapenko O.V. 1 , Sorokina T.P. 1 , Doronin V.P. 1
Организации
1 Center for New Chemical Technologies, Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Omsk, 644040 Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России V.47.1.3 (АААА-А17-117021450099-9)

Реферат: Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed in cracking of a mixture of vacuum gas oil with sunflower oil was examined. It was found that the process of deoxygenation of oxygen-containing compounds can be controlled by varying the molar ratio between magnesium and aluminum in the mixed oxides. For catalyst samples containing mixed oxides with large Mg : Al molar ratios, the content of carbon dioxide in inorganic products grows, which is indicative of the increased activity of the decarboxylation reaction. In addition, the results of catalytic tests demonstrate that the highest conversion and yield of the benzine fraction are observed for catalyst samples containing mixed oxides with small magnesium-to-aluminum ratios of 0.32 : 1 and 0.49 : 1. A high activity of hydrogen-transfer reactions is observed for these samples, which leads to a decrease in the yield of light olefins. Thus, it is advisable, for obtaining an increased yield of C3 and C4 olefins, to include into the composition
Библиографическая ссылка: Lipin P.V. , Potapenko O.V. , Sorokina T.P. , Doronin V.P.
Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions
Russian Journal of Applied Chemistry. 2019. V.92. N10. P.1383-1391. DOI: 10.1134/S1070427219100082 WOS Scopus РИНЦ CAPlusCA OpenAlex ЦНХТ ID
Оригинальная: Липин П.В. , Потапенко О.В. , Сорокина Т.П. , Доронин В.П.
Каталитический крекинг смеси вакуумного газойля и растительного масла в присутствии добавки смешанного Mg-Al оксида различного состава
Журнал прикладной химии. 2019. Т.92. №10. С.1291-1300. DOI: 10.1134/S0044461819100086 РИНЦ OpenAlex ЦНХТ ID
Даты:
Поступила в редакцию: 20 мар. 2019 г.
Принята к публикации: 3 июл. 2019 г.
Опубликована в печати: 1 окт. 2019 г.
Опубликована online: 11 дек. 2019 г.
Идентификаторы БД:
Web of science: WOS:000510661600008
Scopus: 2-s2.0-85076397418
РИНЦ: 43221137
Chemical Abstracts: 2019:2393103
Chemical Abstracts (print): 172:191577
OpenAlex: W2994626033
ЦНХТ ID: 2479
Цитирование в БД:
БД Цитирований
Scopus 1
Web of science 2
OpenAlex 2
Альметрики: