Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions Full article
| Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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| Output data | Year: 2019, Volume: 92, Number: 10, Pages: 1383-1391 Pages count : 9 DOI: 10.1134/S1070427219100082 | ||
| Tags | mixed oxide, catalytic cracking, vegetable oil, hydrogen-transfer reactions | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.47.1.3 (АААА-А17-117021450099-9) |
Abstract:
Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed in cracking of a mixture of vacuum gas oil with sunflower oil was examined. It was found that the process of deoxygenation of oxygen-containing compounds can be controlled by varying the molar ratio between magnesium and aluminum in the mixed oxides. For catalyst samples containing mixed oxides with large Mg : Al molar ratios, the content of carbon dioxide in inorganic products grows, which is indicative of the increased activity of the decarboxylation reaction. In addition, the results of catalytic tests demonstrate that the highest conversion and yield of the benzine fraction are observed for catalyst samples containing mixed oxides with small magnesium-to-aluminum ratios of 0.32 : 1 and 0.49 : 1. A high activity of hydrogen-transfer reactions is observed for these samples, which leads to a decrease in the yield of light olefins. Thus, it is advisable, for obtaining an increased yield of C3 and C4 olefins, to include into the composition
Cite:
Lipin P.V.
, Potapenko O.V.
, Sorokina T.P.
, Doronin V.P.
Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions
Russian Journal of Applied Chemistry. 2019. V.92. N10. P.1383-1391. DOI: 10.1134/S1070427219100082 WOS Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions
Russian Journal of Applied Chemistry. 2019. V.92. N10. P.1383-1391. DOI: 10.1134/S1070427219100082 WOS Scopus РИНЦ ANCAN OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Original:
Липин П.В.
, Потапенко О.В.
, Сорокина Т.П.
, Доронин В.П.
Каталитический крекинг смеси вакуумного газойля и растительного масла в присутствии добавки смешанного Mg-Al оксида различного состава
Журнал прикладной химии. 2019. Т.92. №10. С.1291-1300. DOI: 10.1134/S0044461819100086 РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Каталитический крекинг смеси вакуумного газойля и растительного масла в присутствии добавки смешанного Mg-Al оксида различного состава
Журнал прикладной химии. 2019. Т.92. №10. С.1291-1300. DOI: 10.1134/S0044461819100086 РИНЦ OpenAlex publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | Mar 20, 2019 |
| Accepted: | Jul 3, 2019 |
| Published print: | Oct 1, 2019 |
| Published online: | Dec 11, 2019 |
Identifiers:
| Web of science: | WOS:000510661600008 |
| Scopus: | 2-s2.0-85076397418 |
| Elibrary: | 43221137 |
| Chemical Abstracts: | 2019:2393103 |
| Chemical Abstracts (print): | 172:191577 |
| OpenAlex: | W2994626033 |
| publication_identifier.sciact_ihcp_identifier_type: | 2479 |