The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas | Sciact - CRIS-система Института катализа

The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2024, Том: 65, Номер: 1, Страницы: 66-74 Страниц : 9 DOI: 10.1134/s0023158424010051

Ключевые слова

diesel fuel, structured catalyst, autothermal reforming, synthesis gas, fuel cell, hydrogen

Авторы

Shilov V.A. ^1,2 , Burmatova M.A. ^1,2 , Belyaev V.D. ¹ , Potemkin D.I. ^1,2 , Snytnikov P.V. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Novosibirsk State University, Novosibirsk, 630090 Russia

Информация о финансировании (1)

Российский научный фонд

19-19-00257

The influence of platinum additives on the properties of rhodium catalysts in the processes of steam reforming and autothermal reforming of diesel fuel was investigated. It was found that Rh/CZF was more active compared to the bimetallic sample Rh–Pt/CZF: the degree of fuel conversion in its presence was higher, and the concentration of reaction by-products was lower. The proposed two-zone Pt/CZF + Rh/CZF structured honeycomb catalyst demonstrated stable performance and high activity in the autothermal reforming of commercial diesel fuel. However, the presence of platinum in the frontal zone of the catalyst reduced its resistance to coking compared to the rhodium-containing sample. The results obtained are of practical significance in the development of efficient systems for the conversion of heavy hydrocarbons into synthesis gas.

Shilov V.A. , Burmatova M.A. , Belyaev V.D. , Potemkin D.I. , Snytnikov P.V.
The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas
Kinetics and Catalysis. 2024. V.65. N1. P.66-74. DOI: 10.1134/s0023158424010051 WOS Scopus РИНЦ CAPlus OpenAlex

Шилов В.А. , Бурматова М.А. , Беляев В.Д. , Потемкин Д.И. , Снытников П.В.
Влияние добавок Pt на активность и стабильность Rh-содержащего катализатора конверсии дизельного топлива в синтез-газ
Кинетика и катализ. 2024. Т.65. №1. С.78-86. DOI: 10.31857/S0453881124010079 РИНЦ OpenAlex

Поступила в редакцию:	25 июл. 2023 г.
Принята к публикации:	2 окт. 2023 г.
Опубликована в печати:	1 февр. 2024 г.
Опубликована online:	27 апр. 2024 г.

Web of science:	WOS:001210717700003
Scopus:	2-s2.0-85191656251
РИНЦ:	67308022
Chemical Abstracts:	2024:924979
OpenAlex:	W4395690339

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