The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2024, Volume: 65, Number: 1, Pages: 66-74 Pages count : 9 DOI: 10.1134/s0023158424010051 | ||||
| Tags | diesel fuel, structured catalyst, autothermal reforming, synthesis gas, fuel cell, hydrogen | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 19-19-00257 |
Abstract:
The influence of platinum additives on the properties of rhodium catalysts in the processes of steam reforming and autothermal reforming of diesel fuel was investigated. It was found that Rh/CZF was more active compared to the bimetallic sample Rh–Pt/CZF: the degree of fuel conversion in its presence was higher, and the concentration of reaction by-products was lower. The proposed two-zone Pt/CZF + Rh/CZF structured honeycomb catalyst demonstrated stable performance and high activity in the autothermal reforming of commercial diesel fuel. However, the presence of platinum in the frontal zone of the catalyst reduced its resistance to coking compared to the rhodium-containing sample. The results obtained are of practical significance in the development of efficient systems for the conversion of heavy hydrocarbons into synthesis gas.
Cite:
Shilov V.A.
, Burmatova M.A.
, Belyaev V.D.
, Potemkin D.I.
, Snytnikov P.V.
The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas
Kinetics and Catalysis. 2024. V.65. N1. P.66-74. DOI: 10.1134/s0023158424010051 WOS Scopus РИНЦ AN OpenAlex
The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas
Kinetics and Catalysis. 2024. V.65. N1. P.66-74. DOI: 10.1134/s0023158424010051 WOS Scopus РИНЦ AN OpenAlex
Original:
Шилов В.А.
, Бурматова М.А.
, Беляев В.Д.
, Потемкин Д.И.
, Снытников П.В.
Влияние добавок Pt на активность и стабильность Rh-содержащего катализатора конверсии дизельного топлива в синтез-газ
Кинетика и катализ. 2024. Т.65. №1. С.78-86. DOI: 10.31857/S0453881124010079 РИНЦ OpenAlex
Влияние добавок Pt на активность и стабильность Rh-содержащего катализатора конверсии дизельного топлива в синтез-газ
Кинетика и катализ. 2024. Т.65. №1. С.78-86. DOI: 10.31857/S0453881124010079 РИНЦ OpenAlex
Dates:
| Submitted: | Jul 25, 2023 |
| Accepted: | Oct 2, 2023 |
| Published print: | Feb 1, 2024 |
| Published online: | Apr 27, 2024 |
Identifiers:
| Web of science: | WOS:001210717700003 |
| Scopus: | 2-s2.0-85191656251 |
| Elibrary: | 67308022 |
| Chemical Abstracts: | 2024:924979 |
| OpenAlex: | W4395690339 |