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Hydrogen as the Key Factor Controlling the Efficiency of Carbon Nanofibers Synthesis from Ethylene Научная публикация

Журнал Fuel
ISSN: 0016-2361 , E-ISSN: 1873-7153
Вых. Данные Год: 2024, Том: 375, Номер статьи : 132542, Страниц : 15 DOI: 10.1016/j.fuel.2024.132542
Ключевые слова Nickel-copper catalyst; Ethylene; Hydrogen-assisted catalytic chemical vapor deposition; Carbon nanofibers; Characterization
Авторы Afonnikova Sofya D. 1 , Gilin Danil A. 1 , Veselov Grigory B. 1 , Trenikhin Mikhail V. 2 , Shubin Yury V. 3 , Ayupov Artem B. 1 , Mishakov Ilya V. 1 , Vedyagin Aleksey A. 1
Организации
1 Boreskov Institute of Catalysis SB RAS, Lavrentyev Ave. 5, Novosibirsk 630090, Russia
2 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Neftezavodskaya St. 54, Omsk 644040, Russia
3 Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentyev Ave. 3, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0034

Реферат: Carbon nanofibers with specified textural characteristics, obtained via catalytic chemical vapor deposition of various hydrocarbons, attract growing interest from both scientists and industrialists. In the present work, the optimal hydrogen content in terms of the carbon accumulation rate, process selectivity, and productivity of the Ni-Cu catalyst was found to be in the range of 40–70 vol%. As was revealed by the X-ray diffraction analysis, the catalytic particles are represented by a solid Ni-Cu solution based on the fcc lattice of Ni, and their composition does not depend on the hydrogen concentration. As found, the introduction of an optimal hydrogen amount into the initial reaction mixture decreases AD/AG (from 2.59 to 2.43) and increases both specific surface area (from 127 to 165 m2/g) and total pore volume (from 0.15 to 0.26 cm3/g). Thus, the effect of hydrogen on the decomposition of ethylene over self-dispersing catalysts is studied for the first time.
Библиографическая ссылка: Afonnikova S.D. , Gilin D.A. , Veselov G.B. , Trenikhin M.V. , Shubin Y.V. , Ayupov A.B. , Mishakov I.V. , Vedyagin A.A.
Hydrogen as the Key Factor Controlling the Efficiency of Carbon Nanofibers Synthesis from Ethylene
Fuel. 2024. V.375. 132542 :1-15. DOI: 10.1016/j.fuel.2024.132542 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 31 мая 2024 г.
Принята к публикации: 15 июл. 2024 г.
Опубликована online: 19 июл. 2024 г.
Опубликована в печати: 1 нояб. 2024 г.
Идентификаторы БД:
Web of science: WOS:001275381600001
Scopus: 2-s2.0-85199103115
РИНЦ: 71733640
Chemical Abstracts: 2024:1591978
OpenAlex: W4400806409
Цитирование в БД:
БД Цитирований
Scopus 3
Web of science 2
OpenAlex 2
РИНЦ 1
Альметрики: