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Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes Full article

Journal Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052
Output data Year: 2012, Volume: 14, Number: 17, Pages: 4310-4313 Pages count : 4 DOI: 10.1021/ol3015122
Tags BIOMIMETIC NONHEME IRON; HYDROGEN-PEROXIDE; SYSTEM HYDROGEN; HYDROCARBON OXYGENATIONS; ALKANE HYDROXYLATION; ACETIC-ACID; OLEFINS; EPOXIDATION; Fe; ACTIVATION
Authors Ottenbacher Roman V. 1 , Samsonenko Denis G. 2 , Talsi Evgenii P. 3 , Bryliakov Konstantin P. 3
Affiliations
1 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
2 Nikolaev Institute of Inorganic Chemistry, Pr. Lavrentieva 3, Novosibirsk 630090, Russian Federation
3 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation

Funding (1)

1 Russian Foundation for Basic Research 12-03-00782

Abstract: Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic CH groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
Cite: Ottenbacher R.V. , Samsonenko D.G. , Talsi E.P. , Bryliakov K.P.
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes
Organic Letters. 2012. V.14. N17. P.4310-4313. DOI: 10.1021/ol3015122 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: May 3, 2012
Published online: Jul 2, 2012
Published print: Sep 7, 2012
Identifiers:
Web of science: WOS:000308390000004
Scopus: 2-s2.0-84866034562
Elibrary: 20480428
Chemical Abstracts: 2012:949357
Chemical Abstracts (print): 157:356068
OpenAlex: W2327161573
Citing:
DB Citing
Web of science 105
Scopus 114
Elibrary 100
OpenAlex 119
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