Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes Full article
| Journal |
Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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| Output data | Year: 2012, Volume: 14, Number: 17, Pages: 4310-4313 Pages count : 4 DOI: 10.1021/ol3015122 | ||||||
| Tags | BIOMIMETIC NONHEME IRON; HYDROGEN-PEROXIDE; SYSTEM HYDROGEN; HYDROCARBON OXYGENATIONS; ALKANE HYDROXYLATION; ACETIC-ACID; OLEFINS; EPOXIDATION; Fe; ACTIVATION | ||||||
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 12-03-00782 |
Abstract:
Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C H groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
Cite:
Ottenbacher R.V.
, Samsonenko D.G.
, Talsi E.P.
, Bryliakov K.P.
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes
Organic Letters. 2012. V.14. N17. P.4310-4313. DOI: 10.1021/ol3015122 WOS Scopus РИНЦ OpenAlex ANCAN
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes
Organic Letters. 2012. V.14. N17. P.4310-4313. DOI: 10.1021/ol3015122 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | May 3, 2012 |
| Published online: | Jul 2, 2012 |
| Published print: | Sep 7, 2012 |
Identifiers:
| ≡ Web of science: | WOS:000308390000004 |
| ≡ Scopus: | 2-s2.0-84866034562 |
| ≡ Elibrary: | 20480428 |
| ≡ OpenAlex: | W2327161573 |
| ≡ Chemical Abstracts: | 2012:949357 |
| ≡ Chemical Abstracts (print): | 157:356068 |