Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme | Sciact - CRIS-система Института катализа

Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme Научная публикация

Журнал

Open Chemistry
ISSN: 2391-5420

Вых. Данные

Год: 2024, Том: 22, Номер: 1, Номер статьи : 20240118, Страниц : 15 DOI: 10.1515/chem-2024-0118

Ключевые слова

ethanol steam reforming; nanocomposite spinel + perovskite supports + Ni + Ru; one-pot synthesis with the Pluronic P123 copolymer; surface sites; FTIRS of adsorbed CO

Авторы

Massalimova Bakytgul ¹ , Sadykov Vladislav ^2,4 , Totenova Nurzada ³ , Fedorova Julia ² , Glazneva Tatyana ² , Krieger Tamara ² , Rogov Vladimir ^2,4 , Ishchenko Arkady ²

Организации

1	Department of Chemistry and Chemical Technology, Manash Kozybayev North Kazakhstan University, Pushkin Str 86, 150000, Petropavl, Kazakhstan
2	Federal Research Center, Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
3	Department of Chemistry and Chemical Technology, M. Kh. Dulaty Taraz Regional University, Taraz, 080000, Kazakhstan
4	Department of Natural Sciences, Novosibirsk State University, 630090, Novosibirsk, Russia

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	075-12-2021-697
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	FWUR-2024-0033

Mesoporous MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) nanocomposites were prepared by a cost-effective one-pot procedure with the Pluronic P123 copolymer and Ni + Ru active components were supported on them by wet impregnation. The real structure of samples was studied by X-ray diffraction and transmission electron microscopy with energy-dispersive X-ray spectroscopy, surface properties were determined by Fourier transform infrared spectroscopy of adsorbed CO, reactivity was evaluated by temperature programmed reduction by H2, and catalytic activity was tested in ethanol steam reforming (ESR). Disordering of the real structure of nanocomposite supports due to incorporation of transition metal cations into MgAl2O4 results in the development of a metal–support interface and domination of single surface metal centers. This provides a high catalytic activity in the ESR reaction in the intermediate temperature range ∼550°C, close to that of the best known catalysts, and stability to coking. A higher activity for the Pr-containing catalyst is provided by the high reactivity of surface oxygen species bound with Pr cations.

Massalimova B. , Sadykov V. , Totenova N. , Fedorova J. , Glazneva T. , Krieger T. , Rogov V. , Ishchenko A.
Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme
Open Chemistry. 2024. V.22. N1. 20240118 :1-15. DOI: 10.1515/chem-2024-0118 WOS OpenAlex

Поступила в редакцию:	9 сент. 2024 г.
Принята к публикации:	18 нояб. 2024 г.
Опубликована в печати:	11 дек. 2024 г.
Опубликована online:	11 дек. 2024 г.

Web of science:	WOS:001374640400001
OpenAlex:	W4405279292

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