Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme | Sciact - CRIS-system of Boreskov Institute of Catalysis

Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme Full article

Journal

Open Chemistry
ISSN: 2391-5420

Output data

Year: 2024, Volume: 22, Number: 1, Article number : 20240118, Pages count : 15 DOI: 10.1515/chem-2024-0118

Tags

ethanol steam reforming; nanocomposite spinel + perovskite supports + Ni + Ru; one-pot synthesis with the Pluronic P123 copolymer; surface sites; FTIRS of adsorbed CO

Authors

Massalimova Bakytgul ¹ , Sadykov Vladislav ^2,4 , Totenova Nurzada ³ , Fedorova Julia ² , Glazneva Tatyana ² , Krieger Tamara ² , Rogov Vladimir ^2,4 , Ishchenko Arkady ²

Affiliations

1	Department of Chemistry and Chemical Technology, Manash Kozybayev North Kazakhstan University, Pushkin Str 86, 150000, Petropavl, Kazakhstan
2	Federal Research Center, Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
3	Department of Chemistry and Chemical Technology, M. Kh. Dulaty Taraz Regional University, Taraz, 080000, Kazakhstan
4	Department of Natural Sciences, Novosibirsk State University, 630090, Novosibirsk, Russia

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	075-12-2021-697
2	Ministry of Science and Higher Education of the Russian Federation	FWUR-2024-0033

Mesoporous MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) nanocomposites were prepared by a cost-effective one-pot procedure with the Pluronic P123 copolymer and Ni + Ru active components were supported on them by wet impregnation. The real structure of samples was studied by X-ray diffraction and transmission electron microscopy with energy-dispersive X-ray spectroscopy, surface properties were determined by Fourier transform infrared spectroscopy of adsorbed CO, reactivity was evaluated by temperature programmed reduction by H2, and catalytic activity was tested in ethanol steam reforming (ESR). Disordering of the real structure of nanocomposite supports due to incorporation of transition metal cations into MgAl2O4 results in the development of a metal–support interface and domination of single surface metal centers. This provides a high catalytic activity in the ESR reaction in the intermediate temperature range ∼550°C, close to that of the best known catalysts, and stability to coking. A higher activity for the Pr-containing catalyst is provided by the high reactivity of surface oxygen species bound with Pr cations.

Massalimova B. , Sadykov V. , Totenova N. , Fedorova J. , Glazneva T. , Krieger T. , Rogov V. , Ishchenko A.
Efficient and Stable to Coking Catalysts of Ethanol Ssteam Reforming Comprised of Ni + Ru Loaded on MgAl2O4 + LnFe0.7Ni0.3O3 (Ln = La, Pr) Nanocomposites Prepared via Cost-Effective Procedure with Pluronic P123 Copolyme
Open Chemistry. 2024. V.22. N1. 20240118 :1-15. DOI: 10.1515/chem-2024-0118 WOS Scopus РИНЦ OpenAlex

Submitted:	Sep 9, 2024
Accepted:	Nov 18, 2024
Published print:	Dec 11, 2024
Published online:	Dec 11, 2024

Web of science:	WOS:001374640400001
Scopus:	2-s2.0-85213723047
Elibrary:	79909507
OpenAlex:	W4405279292

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