Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors | Sciact - CRIS-система Института катализа

Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Вых. Данные

Год: 2013, Том: 62, Номер: 11, Страницы: 2349-2361 Страниц : 13 DOI: 10.1007/s11172-013-0341-5

Ключевые слова

layered double hydroxide, magnesium, mixed oxides, structure reconstruction, zinc and nickel cations

Авторы

Belskaya O.B. ¹ , Leontʹeva N.N. ¹ , Gulyaeva T.I. ¹ , Cherepanova S.V. ² , Talzi V.P. ¹ , Drozdov V.A. ¹ , Likholobov V.A. ¹

Организации

1	Institute of Hydrocarbons Processing of the Siberian Branch of the Russian Academy of Sciences, 54 Neftezavodskaya ul., 644040 Omsk, Russian Federation.
2	Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 5 Akad. Lavrentieva prosp., 630090 Novosibirsk, Russian Federation

Influence of the nature of a doubly charged cation in the layered double hydroxides (LDH) on the conditions of formation and properties of mixed oxide phase MAlO x (M = Mg2+, Zn2+ and Ni2+), its ability to reconstruct the structure of the original precursor under contact with water has been studied. Hydrotalcite-like compounds and corresponding oxides with different M2+: M3+ ratio were investigated by XRD, TEM, TG-DTG-DTA, 27Al NMR, N2 adsorption, and differentiating dissolution. It has been found that the nature of the cation M2+ influences the conditions of LDH thermal decomposition, structural and textural characteristics of the formed mixed oxides. The obtained data can be used to synthesize the oxide supports with desired acid-base and adsorption properties.

Belskaya O.B. , Leontʹeva N.N. , Gulyaeva T.I. , Cherepanova S.V. , Talzi V.P. , Drozdov V.A. , Likholobov V.A.
Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors
Russian Chemical Bulletin. 2013. V.62. N11. P.2349-2361. DOI: 10.1007/s11172-013-0341-5 WOS Scopus РИНЦ CAPlusCA OpenAlex

Бельская О.Б. , Леонтьева Н.Н. , Гуляева Т.И. , Черепанова С.В. , Талзи В.П. , Дроздов В.А. , Лихолобов В.А.
Влияние природы двухзарядного катиона на формирование и свойства смешанных оксидов MAlOx (M = Mg2+, Zn2+, Ni2+), полученных из слоистых гидроксидных предшественников
Известия Академии наук. Серия химическая. 2013. №11. С.2349-2361. РИНЦ

Поступила в редакцию:	14 июн. 2013 г.
Опубликована в печати:	1 нояб. 2013 г.
Опубликована online:	27 июл. 2014 г.

Web of science:	WOS:000339729700011
Scopus:	2-s2.0-84906729863
РИНЦ:	23978654
Chemical Abstracts:	2014:1227365
Chemical Abstracts (print):	161:325661
OpenAlex:	W2089627972

БД	Цитирований
Web of science	19
Scopus	20
РИНЦ	18
OpenAlex	20