Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2013, Volume: 62, Number: 11, Pages: 2349-2361 Pages count : 13 DOI: 10.1007/s11172-013-0341-5 | ||||
| Tags | layered double hydroxide, magnesium, mixed oxides, structure reconstruction, zinc and nickel cations | ||||
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Abstract:
Influence of the nature of a doubly charged cation in the layered double hydroxides (LDH) on the conditions of formation and properties of mixed oxide phase MAlO x (M = Mg2+, Zn2+ and Ni2+), its ability to reconstruct the structure of the original precursor under contact with water has been studied. Hydrotalcite-like compounds and corresponding oxides with different M2+: M3+ ratio were investigated by XRD, TEM, TG-DTG-DTA, 27Al NMR, N2 adsorption, and differentiating dissolution. It has been found that the nature of the cation M2+ influences the conditions of LDH thermal decomposition, structural and textural characteristics of the formed mixed oxides. The obtained data can be used to synthesize the oxide supports with desired acid-base and adsorption properties.
Cite:
Belskaya O.B.
, Leontʹeva N.N.
, Gulyaeva T.I.
, Cherepanova S.V.
, Talzi V.P.
, Drozdov V.A.
, Likholobov V.A.
Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors
Russian Chemical Bulletin. 2013. V.62. N11. P.2349-2361. DOI: 10.1007/s11172-013-0341-5 WOS Scopus РИНЦ ANCAN OpenAlex
Influence of a Doubly Charged Cation Nature on the Formation and Properties of Mixed Oxides MAlO x (M = Mg2+, Zn2+, Ni2+) Obtained from the Layered Hydroxide Precursors
Russian Chemical Bulletin. 2013. V.62. N11. P.2349-2361. DOI: 10.1007/s11172-013-0341-5 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Бельская О.Б.
, Леонтьева Н.Н.
, Гуляева Т.И.
, Черепанова С.В.
, Талзи В.П.
, Дроздов В.А.
, Лихолобов В.А.
Влияние природы двухзарядного катиона на формирование и свойства смешанных оксидов MAlOx (M = Mg2+, Zn2+, Ni2+), полученных из слоистых гидроксидных предшественников
Известия Академии наук. Серия химическая. 2013. №11. С.2349-2361. РИНЦ
Влияние природы двухзарядного катиона на формирование и свойства смешанных оксидов MAlOx (M = Mg2+, Zn2+, Ni2+), полученных из слоистых гидроксидных предшественников
Известия Академии наук. Серия химическая. 2013. №11. С.2349-2361. РИНЦ
Dates:
| Submitted: | Jun 14, 2013 |
| Published print: | Nov 1, 2013 |
| Published online: | Jul 27, 2014 |
Identifiers:
| Web of science: | WOS:000339729700011 |
| Scopus: | 2-s2.0-84906729863 |
| Elibrary: | 23978654 |
| Chemical Abstracts: | 2014:1227365 |
| Chemical Abstracts (print): | 161:325661 |
| OpenAlex: | W2089627972 |