Sciact
  • EN
  • RU

Effect of Iron Content on Selectivity in Isomerization of α-Pinene Oxide to Campholenic Aldehyde over Fe-MMM-2 and Fe-VSB-5 Научная публикация

Журнал Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Вых. Данные Год: 2014, Том: 469, Страницы: 427-433 Страниц : 7 DOI: 10.1016/j.apcata.2013.10.016
Ключевые слова Fe-containing mesoporous materials, Fe-VSB-5, Isomerization of α-pinene oxide, Lewis acidity
Авторы Timofeeva M.N. 1,2 , Panchenko V.N. 1 , Hasan Zubair 3 , Khan Nazmul Abedin 3 , Melʹgunov M.S. 1 , Abel A.A. 1 , Matrosova M.M. 1 , Volcho K.P. 4 , Jhung Sung Hwa 3
Организации
1 Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State Technichal University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
4 Novosibirsk Institute of Organic Chemistry SB RAS, Prospekt Akad. Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Информация о финансировании (3)

1 Министерство образования и науки Российской Федерации 2012-1.5-12-000-1013-002
2 National Research Foundation of Korea 2012R1A1A2004528
3 Федеральное агентство научных организаций России V.44.2.12.

Реферат: Isomerization of α-pinene oxide to campholenic aldehyde (CA) was investigated over Fe-containing mesoporous mesophase materials (Fe-MMM-2) and microporous nickel phosphate molecular sieves (Fe-VSB-5). Activity and selectivity of reaction towards CA over Fe-containing materials was found to depend on iron content in materials that affects oligomeric state of Fe and amount of Lewis acid sites. In the presence of Fe-VSB-5 selectivity towards CA increased with increase in iron content in structure, while that decreased in the presence of Fe-MMM-2. This phenomenon is related to change in agglomeration of iron species in Fe-MMM-2 structure. The high selectivity towards CA in the presence of Fe-VSB-5 was suggested to arise from unique structure of these materials, which favours shape selectivity.
Библиографическая ссылка: Timofeeva M.N. , Panchenko V.N. , Hasan Z. , Khan N.A. , Melʹgunov M.S. , Abel A.A. , Matrosova M.M. , Volcho K.P. , Jhung S.H.
Effect of Iron Content on Selectivity in Isomerization of α-Pinene Oxide to Campholenic Aldehyde over Fe-MMM-2 and Fe-VSB-5
Applied Catalysis A: General. 2014. V.469. P.427-433. DOI: 10.1016/j.apcata.2013.10.016 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 12 июл. 2013 г.
Принята к публикации: 8 окт. 2013 г.
Опубликована online: 17 окт. 2013 г.
Опубликована в печати: 17 янв. 2014 г.
Идентификаторы БД:
Web of science: WOS:000329266500051
Scopus: 2-s2.0-84887041009
РИНЦ: 21861062
Chemical Abstracts: 2013:1919890
Chemical Abstracts (print): 160:102944
OpenAlex: W2008660858
Цитирование в БД:
БД Цитирований
Web of science 29
Scopus 31
РИНЦ 31
OpenAlex 31
Альметрики: