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Effect of Iron Content on Selectivity in Isomerization of α-Pinene Oxide to Campholenic Aldehyde over Fe-MMM-2 and Fe-VSB-5 Full article

Journal Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Output data Year: 2014, Volume: 469, Pages: 427-433 Pages count : 7 DOI: 10.1016/j.apcata.2013.10.016
Tags Fe-containing mesoporous materials, Fe-VSB-5, Isomerization of α-pinene oxide, Lewis acidity
Authors Timofeeva M.N. 1,2 , Panchenko V.N. 1 , Hasan Zubair 3 , Khan Nazmul Abedin 3 , Melʹgunov M.S. 1 , Abel A.A. 1 , Matrosova M.M. 1 , Volcho K.P. 4 , Jhung Sung Hwa 3
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State Technichal University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
4 Novosibirsk Institute of Organic Chemistry SB RAS, Prospekt Akad. Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Funding (3)

1 The Ministry of Education and Science of the Russian Federation 2012-1.5-12-000-1013-002
2 National Research Foundation of Korea 2012R1A1A2004528
3 Federal Agency for Scientific Organizations V.44.2.12.

Abstract: Isomerization of α-pinene oxide to campholenic aldehyde (CA) was investigated over Fe-containing mesoporous mesophase materials (Fe-MMM-2) and microporous nickel phosphate molecular sieves (Fe-VSB-5). Activity and selectivity of reaction towards CA over Fe-containing materials was found to depend on iron content in materials that affects oligomeric state of Fe and amount of Lewis acid sites. In the presence of Fe-VSB-5 selectivity towards CA increased with increase in iron content in structure, while that decreased in the presence of Fe-MMM-2. This phenomenon is related to change in agglomeration of iron species in Fe-MMM-2 structure. The high selectivity towards CA in the presence of Fe-VSB-5 was suggested to arise from unique structure of these materials, which favours shape selectivity.
Cite: Timofeeva M.N. , Panchenko V.N. , Hasan Z. , Khan N.A. , Melʹgunov M.S. , Abel A.A. , Matrosova M.M. , Volcho K.P. , Jhung S.H.
Effect of Iron Content on Selectivity in Isomerization of α-Pinene Oxide to Campholenic Aldehyde over Fe-MMM-2 and Fe-VSB-5
Applied Catalysis A: General. 2014. V.469. P.427-433. DOI: 10.1016/j.apcata.2013.10.016 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 12, 2013
Accepted: Oct 8, 2013
Published online: Oct 17, 2013
Published print: Jan 17, 2014
Identifiers:
Web of science: WOS:000329266500051
Scopus: 2-s2.0-84887041009
Elibrary: 21861062
Chemical Abstracts: 2013:1919890
Chemical Abstracts (print): 160:102944
OpenAlex: W2008660858
Citing:
DB Citing
Web of science 29
Scopus 31
Elibrary 31
OpenAlex 31
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