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Rearrangement of alfa-Pinene Oxide to Campholenic Aldehyde over the Trimesate Metal-Organic Frameworks MIL-100, MIL-110 and MIL-96 Научная публикация

Журнал Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694
Вых. Данные Год: 2014, Том: 311, Страницы: 114-120 Страниц : 7 DOI: 10.1016/j.jcat.2013.11.006
Ключевые слова Campholenic aldehyde, Isomerization of α-pinene oxide, Lewis acidity, Metal-organic framework
Авторы Timofeeva Maria N. 1,2 , Panchenko Valentina N. 1 , Abel Anna A. 1 , Khan Nazmul Abedin 3 , Ahmed Imteaz 3 , Ayupov Artem B. 1 , Volcho Konstantin P. 4 , Jhung Sung Hwa 3
Организации
1 Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State Technical University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3 Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
4 Novosibirsk Institute of Organic Chemistry SB RAS, Prospekt Akad. Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Информация о финансировании (3)

1 Министерство образования и науки Российской Федерации 2012-1.5-12-000-1013-002
2 Федеральное агентство научных организаций России V.44.2.12.
3 National Research Foundation of Korea 2013R1A2A2A01007176

Реферат: 110(Al) and MIL-96(Al), was investigated with a combination of physicochemical and catalytic approaches in the rearrangement of alfa-pinene oxide to campholenic aldehyde (CA). The investigation of Lewis acidity was done by EPR and IR spectroscopy using 2,2',6,6'-tetramethyl-1-piperidinyoxyl radical and benzonitrile as the probe molecules, respectively. For Al-BTCs, both these methods showed a decrease in the amount of Lewis acid sites as follows: MIL-100 > MIL-110 > MIL-96. The reaction rate and selectivity toward CA also decreased in the same order. A relatively good correlation between selectivity toward CA and the electronegativity of the metal ion was found for isostructural MIL-100(Al, Fe and Cr). The selectivity toward CA decreased in the order: MIL-100(Al) > MIL-100(Fe) > MIL-100(Cr). The high selectivity toward CA in the presence of MIL-100 has been suggested to originate from the unique structure of this material, which favors shape selectivity
Библиографическая ссылка: Timofeeva M.N. , Panchenko V.N. , Abel A.A. , Khan N.A. , Ahmed I. , Ayupov A.B. , Volcho K.P. , Jhung S.H.
Rearrangement of alfa-Pinene Oxide to Campholenic Aldehyde over the Trimesate Metal-Organic Frameworks MIL-100, MIL-110 and MIL-96
Journal of Catalysis. 2014. V.311. P.114-120. DOI: 10.1016/j.jcat.2013.11.006 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 22 сент. 2013 г.
Принята к публикации: 7 нояб. 2013 г.
Опубликована online: 18 дек. 2013 г.
Опубликована в печати: 1 мар. 2014 г.
Идентификаторы БД:
Web of science: WOS:000333489500013
Scopus: 2-s2.0-84890828716
РИНЦ: 21862030
Chemical Abstracts: 2014:283576
Chemical Abstracts (print): 160:399218
OpenAlex: W2023427922
Цитирование в БД:
БД Цитирований
Web of science 34
Scopus 40
РИНЦ 39
OpenAlex 39
Альметрики: