Rearrangement of alfa-Pinene Oxide to Campholenic Aldehyde over the Trimesate Metal-Organic Frameworks MIL-100, MIL-110 and MIL-96 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Rearrangement of alfa-Pinene Oxide to Campholenic Aldehyde over the Trimesate Metal-Organic Frameworks MIL-100, MIL-110 and MIL-96 Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2014, Volume: 311, Pages: 114-120 Pages count : 7 DOI: 10.1016/j.jcat.2013.11.006

Tags

Campholenic aldehyde, Isomerization of α-pinene oxide, Lewis acidity, Metal-organic framework

Authors

Timofeeva Maria N. ^1,2 , Panchenko Valentina N. ¹ , Abel Anna A. ¹ , Khan Nazmul Abedin ³ , Ahmed Imteaz ³ , Ayupov Artem B. ¹ , Volcho Konstantin P. ⁴ , Jhung Sung Hwa ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State Technical University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
4	Novosibirsk Institute of Organic Chemistry SB RAS, Prospekt Akad. Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Funding (3)

1	The Ministry of Education and Science of the Russian Federation	2012-1.5-12-000-1013-002
2	Federal Agency for Scientific Organizations	V.44.2.12.
3	National Research Foundation of Korea	2013R1A2A2A01007176

110(Al) and MIL-96(Al), was investigated with a combination of physicochemical and catalytic approaches in the rearrangement of alfa-pinene oxide to campholenic aldehyde (CA). The investigation of Lewis acidity was done by EPR and IR spectroscopy using 2,2',6,6'-tetramethyl-1-piperidinyoxyl radical and benzonitrile as the probe molecules, respectively. For Al-BTCs, both these methods showed a decrease in the amount of Lewis acid sites as follows: MIL-100 > MIL-110 > MIL-96. The reaction rate and selectivity toward CA also decreased in the same order. A relatively good correlation between selectivity toward CA and the electronegativity of the metal ion was found for isostructural MIL-100(Al, Fe and Cr). The selectivity toward CA decreased in the order: MIL-100(Al) > MIL-100(Fe) > MIL-100(Cr). The high selectivity toward CA in the presence of MIL-100 has been suggested to originate from the unique structure of this material, which favors shape selectivity

Timofeeva M.N. , Panchenko V.N. , Abel A.A. , Khan N.A. , Ahmed I. , Ayupov A.B. , Volcho K.P. , Jhung S.H.
Rearrangement of alfa-Pinene Oxide to Campholenic Aldehyde over the Trimesate Metal-Organic Frameworks MIL-100, MIL-110 and MIL-96
Journal of Catalysis. 2014. V.311. P.114-120. DOI: 10.1016/j.jcat.2013.11.006 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Sep 22, 2013
Accepted:	Nov 7, 2013
Published online:	Dec 18, 2013
Published print:	Mar 1, 2014

Web of science:	WOS:000333489500013
Scopus:	2-s2.0-84890828716
Elibrary:	21862030
Chemical Abstracts:	2014:283576
Chemical Abstracts (print):	160:399218
OpenAlex:	W2023427922

DB	Citing
Web of science	34
Scopus	40
Elibrary	39
OpenAlex	39