On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts | Sciact - CRIS-система Института катализа

On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts Обзор

Конференция

IX International Conference “Mechanisms of Catalytic Reactions”
22-25 окт. 2012 , Санкт-Петербург

Журнал

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Вых. Данные

Год: 2013, Том: 56, Номер: 11, Страницы: 914-922 Страниц : 9 DOI: 10.1007/s11244-013-0055-9

Ключевые слова

Active sites, Living polymerization, Mechanism, o-Fluorinated, Post-metallocene, Titanium

Авторы

Talsi Evgenii P. ¹ , Bryliakov Konstantin P. ¹

Организации

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federatio

Информация о финансировании (1)

Российский фонд фундаментальных исследований

12-03-00133

Group 4 bis(phenoxyimine) and related complexes are highly active olefin polymerization catalysts of the post-metallocene family. When activated with methylalumoxane, titanium complexes bearing o-fluoroaryl substituents can conduct living polymerization of ethylene and propylene. In spite of more than 10-year history of such catalysts, the origin of living behavior of such catalysts remains open to questions. This work presents the state of the art of the discussion on the living nature of single-site post-metallocene titanium based catalysts bearing o-fluoroaryl substituents. Recent experimental and theoretical results are discussed.

Talsi E.P. , Bryliakov K.P.
On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts
Topics in Catalysis. 2013. V.56. N11. P.914-922. DOI: 10.1007/s11244-013-0055-9 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	14 мая 2013 г.
Опубликована в печати:	1 авг. 2013 г.

Web of science:	WOS:000321664200008
Scopus:	2-s2.0-84880407423
РИНЦ:	20442067
Chemical Abstracts:	2013:766564
Chemical Abstracts (print):	159:134114
OpenAlex:	W2032292908

БД	Цитирований
Web of science	9
Scopus	10
РИНЦ	10
OpenAlex	12