On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts Review
| Conference |
IX International Conference “Mechanisms of Catalytic Reactions” 22-25 Oct 2012 , Санкт-Петербург |
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| Journal |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Output data | Year: 2013, Volume: 56, Number: 11, Pages: 914-922 Pages count : 9 DOI: 10.1007/s11244-013-0055-9 | ||
| Tags | Active sites, Living polymerization, Mechanism, o-Fluorinated, Post-metallocene, Titanium | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 12-03-00133 |
Abstract:
Group 4 bis(phenoxyimine) and related complexes are highly active olefin polymerization catalysts of the post-metallocene family. When activated with methylalumoxane, titanium complexes bearing o-fluoroaryl substituents can conduct living polymerization of ethylene and propylene. In spite of more than 10-year history of such catalysts, the origin of living behavior of such catalysts remains open to questions. This work presents the state of the art of the discussion on the living nature of single-site post-metallocene titanium based catalysts bearing o-fluoroaryl substituents. Recent experimental and theoretical results are discussed.
Cite:
Talsi E.P.
, Bryliakov K.P.
On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts
Topics in Catalysis. 2013. V.56. N11. P.914-922. DOI: 10.1007/s11244-013-0055-9 WOS Scopus РИНЦ ANCAN OpenAlex
On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts
Topics in Catalysis. 2013. V.56. N11. P.914-922. DOI: 10.1007/s11244-013-0055-9 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | May 14, 2013 |
| Published print: | Aug 1, 2013 |
Identifiers:
| Web of science: | WOS:000321664200008 |
| Scopus: | 2-s2.0-84880407423 |
| Elibrary: | 20442067 |
| Chemical Abstracts: | 2013:766564 |
| Chemical Abstracts (print): | 159:134114 |
| OpenAlex: | W2032292908 |