Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function | Sciact - CRIS-система Института катализа

Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function Научная публикация

Журнал

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Вых. Данные

Год: 2000, Том: 153, Номер: 1-2, Страницы: 231-236 Страниц : 6 DOI: 10.1016/S1381-1169(99)00352-0

Ключевые слова

13C NMR, 2D NMR, Chlorobenzene, Hydrodechlorination, Nickel and palladium catalysts

Авторы

Yakovlev V.A. ¹ , Terskikh V.V. ¹ , Simagina V.I. ¹ , Likholobov V.A. ¹

Организации

1	Boreskov Institute of Catalysis, Pr. Acad. Lavrentieva, 5, Novosibirsk 630090, Russia

The catalytic hydrodechlorination of chlorobenzene with Ni/C, Pd/C and Ni98Pd2/C in ethanol was studied with 2D and 13C{1H} NMR. Two dechlorination routes of this reaction (ionic and free-radical) are suggested depending upon the nature of the active hydrogen species. At the same time two competitive sources of hydrogen for hydrogenolysis of the CCl bond – molecular hydrogen and solvent (ethanol) molecules – are readily apparent from experiments with molecular deuterium.

Yakovlev V.A. , Terskikh V.V. , Simagina V.I. , Likholobov V.A.
Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function
Journal of Molecular Catalysis A: Chemical. 2000. V.153. N1-2. P.231-236. DOI: 10.1016/S1381-1169(99)00352-0 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	19 апр. 1999 г.
Принята к публикации:	13 сент. 1999 г.
Опубликована в печати:	10 мар. 2000 г.
Опубликована online:	13 мар. 2000 г.

Web of science:	WOS:000085905200026
Scopus:	2-s2.0-0034628690
РИНЦ:	13353151
Chemical Abstracts:	2000:168952
Chemical Abstracts (print):	132:323263
OpenAlex:	W2035752172

БД	Цитирований
Web of science	53
Scopus	54
РИНЦ	56
OpenAlex	60