Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function Full article
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Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2000, Volume: 153, Number: 1-2, Pages: 231-236 Pages count : 6 DOI: 10.1016/S1381-1169(99)00352-0 | ||
| Tags | 13C NMR, 2D NMR, Chlorobenzene, Hydrodechlorination, Nickel and palladium catalysts | ||
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Abstract:
The catalytic hydrodechlorination of chlorobenzene with Ni/C, Pd/C and Ni98Pd2/C in ethanol was studied with 2D and 13C{1H} NMR. Two dechlorination routes of this reaction (ionic and free-radical) are suggested depending upon the nature of the active hydrogen species. At the same time two competitive sources of hydrogen for hydrogenolysis of the CCl bond – molecular hydrogen and solvent (ethanol) molecules – are readily apparent from experiments with molecular deuterium.
Cite:
Yakovlev V.A.
, Terskikh V.V.
, Simagina V.I.
, Likholobov V.A.
Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function
Journal of Molecular Catalysis A: Chemical. 2000. V.153. N1-2. P.231-236. DOI: 10.1016/S1381-1169(99)00352-0 WOS Scopus РИНЦ ANCAN OpenAlex
Liquid Phase Catalytic Hydrodechlorination of Chlorobenzene over Supported Nickel and Palladium Catalysts: An NMR Insight into Solvent Function
Journal of Molecular Catalysis A: Chemical. 2000. V.153. N1-2. P.231-236. DOI: 10.1016/S1381-1169(99)00352-0 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 19, 1999 |
| Accepted: | Sep 13, 1999 |
| Published print: | Mar 10, 2000 |
| Published online: | Mar 13, 2000 |
Identifiers:
| Web of science: | WOS:000085905200026 |
| Scopus: | 2-s2.0-0034628690 |
| Elibrary: | 13353151 |
| Chemical Abstracts: | 2000:168952 |
| Chemical Abstracts (print): | 132:323263 |
| OpenAlex: | W2035752172 |