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Performance of Ba-Containing Catalysts in the Transesterification Reaction of Rapeseed Oil with Methanol Under Flow Conditions Научная публикация

Журнал Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Вых. Данные Год: 2012, Том: 18, Страницы: 156-160 Страниц : 5 DOI: 10.1016/j.catcom.2011.12.008
Ключевые слова Biodiesel, Rapeseed oil, Solid base catalysts, Transesterification, XPS, XRD
Авторы Ivanova A.S. 1 , Sherstyuk O.V. 1 , Bukhtiyarova M.V. 1,2 , Kukushkin R.G. 1,2 , Matvienko L.G. 1 , Plyasova L.M. 1 , Kaichev V.V. 1 , Simonov A.N. 1 , Yakovlev V.A. 1
Организации
1 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2 Novosibirsk state university, Str. Pirogova 2, 630090, Novosibirsk, Russian Federation

Реферат: Long-term performance of two barium-containing catalysts in the transesterification was studied in the flow fixed bed reactor during 50–60 h at the temperature of 200 (228)°C, the pressure of 20 (30)atm and the liquid hourly space velocity of 0.8–2h−1. The performance of the Ba0.04La1.96O3 catalyst is sustained at very high level during 50 h and then declines sharply. The BaAl12O19 catalyst exhibits lower performance but higher stability. The change of the phase or surface composition of the catalysts monitored by X-ray diffraction or X-ray photoelectron spectroscopy are the cause of the diminution of the performance.
Библиографическая ссылка: Ivanova A.S. , Sherstyuk O.V. , Bukhtiyarova M.V. , Kukushkin R.G. , Matvienko L.G. , Plyasova L.M. , Kaichev V.V. , Simonov A.N. , Yakovlev V.A.
Performance of Ba-Containing Catalysts in the Transesterification Reaction of Rapeseed Oil with Methanol Under Flow Conditions
Catalysis Communications. 2012. V.18. P.156-160. DOI: 10.1016/j.catcom.2011.12.008 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 30 сент. 2011 г.
Принята к публикации: 7 дек. 2011 г.
Опубликована online: 13 дек. 2011 г.
Опубликована в печати: 1 февр. 2012 г.
Идентификаторы БД:
Web of science: WOS:000300970600034
Scopus: 2-s2.0-84855454862
РИНЦ: 17971094
Chemical Abstracts: 2012:96311
Chemical Abstracts (print): 156:151265
OpenAlex: W1999123898
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 8
РИНЦ 9
OpenAlex 8
Альметрики: