Performance of Ba-Containing Catalysts in the Transesteriﬁcation Reaction of Rapeseed Oil with Methanol Under Flow Conditions | Sciact - CRIS-system of Boreskov Institute of Catalysis

Performance of Ba-Containing Catalysts in the Transesteriﬁcation Reaction of Rapeseed Oil with Methanol Under Flow Conditions Full article

Journal

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Output data

Year: 2012, Volume: 18, Pages: 156-160 Pages count : 5 DOI: 10.1016/j.catcom.2011.12.008

Tags

Biodiesel, Rapeseed oil, Solid base catalysts, Transesterification, XPS, XRD

Authors

Ivanova A.S. ¹ , Sherstyuk O.V. ¹ , Bukhtiyarova M.V. ^1,2 , Kukushkin R.G. ^1,2 , Matvienko L.G. ¹ , Plyasova L.M. ¹ , Kaichev V.V. ¹ , Simonov A.N. ¹ , Yakovlev V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	Novosibirsk state university, Str. Pirogova 2, 630090, Novosibirsk, Russian Federation

Long-term performance of two barium-containing catalysts in the transesteriﬁcation was studied in the ﬂow ﬁxed bed reactor during 50–60 h at the temperature of 200 (228)°C, the pressure of 20 (30)atm and the liquid hourly space velocity of 0.8–2h−1. The performance of the Ba0.04La1.96O3 catalyst is sustained at very high level during 50 h and then declines sharply. The BaAl12O19 catalyst exhibits lower performance but higher stability. The change of the phase or surface composition of the catalysts monitored by X-ray diffraction or X-ray photoelectron spectroscopy are the cause of the diminution of the performance.

Ivanova A.S. , Sherstyuk O.V. , Bukhtiyarova M.V. , Kukushkin R.G. , Matvienko L.G. , Plyasova L.M. , Kaichev V.V. , Simonov A.N. , Yakovlev V.A.
Performance of Ba-Containing Catalysts in the Transesteriﬁcation Reaction of Rapeseed Oil with Methanol Under Flow Conditions
Catalysis Communications. 2012. V.18. P.156-160. DOI: 10.1016/j.catcom.2011.12.008 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Sep 30, 2011
Accepted:	Dec 7, 2011
Published online:	Dec 13, 2011
Published print:	Feb 1, 2012

Web of science:	WOS:000300970600034
Scopus:	2-s2.0-84855454862
Elibrary:	17971094
Chemical Abstracts:	2012:96311
Chemical Abstracts (print):	156:151265
OpenAlex:	W1999123898

DB	Citing
Web of science	8
Scopus	8
Elibrary	9
OpenAlex	8