Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst | Sciact - CRIS-система Института катализа

Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst Научная публикация

Журнал

Scripta Materialia
ISSN: 1359-6462

Вых. Данные

Год: 2001, Том: 44, Номер: 8-9, Страницы: 1663-1666 Страниц : 4 DOI: 10.1016/S1359-6462(01)00877-6

Ключевые слова

Aero-gel, Catalysis, Electron spin resonance, Nanocrystal, Surface, TEM

Авторы

Richards Ryan ¹ , Mulukutla Ravichandra S. ¹ , Mishakov Ilya ² , Chesnokov Vladimir ² , Volodin Alexander ² , Zaikovski Vladimir ² , Sun Naijian ¹ , Klabunde Kenneth J. ¹

Организации

1	Department of Chemistry, Kansas State University, Manhattan, KS 66506, USA
2	Boreskov Institute Catalysis, Novosibirsk 630090, Russia

Nanocyrstals of MgO having 4 nm average crystallite sizes with 450–550 m2/g surface area were prepared by the Aero-gel preparation method (AP-MgO). Dehydrohalogenation of 1-chlorobutane was performed using AP-MgO as a catalyst; And 1-butene is the selective product formed even after several cycles of 1-chlorobutane injections. AP-MgO was allowed to react with Cl2, which resulted in the formation of a highly reactive adduct which has a capability to selectively chlorinate propane.

Richards R. , Mulukutla R.S. , Mishakov I. , Chesnokov V. , Volodin A. , Zaikovski V. , Sun N. , Klabunde K.J.
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst
Scripta Materialia. 2001. V.44. N8-9. P.1663-1666. DOI: 10.1016/S1359-6462(01)00877-6 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	21 авг. 2000 г.
Принята к публикации:	22 нояб. 2000 г.
Опубликована в печати:	18 мая 2001 г.
Опубликована online:	13 июн. 2001 г.

Web of science:	WOS:000169389400099
Scopus:	2-s2.0-0035906768
РИНЦ:	13385558
Chemical Abstracts:	2001:440766
Chemical Abstracts (print):	135:127683
OpenAlex:	W1983987673

БД	Цитирований
Web of science	38
Scopus	43
РИНЦ	40
OpenAlex	45