Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst Full article

Journal

Scripta Materialia
ISSN: 1359-6462

Output data

Year: 2001, Volume: 44, Number: 8-9, Pages: 1663-1666 Pages count : 4 DOI: 10.1016/S1359-6462(01)00877-6

Tags

Aero-gel, Catalysis, Electron spin resonance, Nanocrystal, Surface, TEM

Authors

Richards Ryan ¹ , Mulukutla Ravichandra S. ¹ , Mishakov Ilya ² , Chesnokov Vladimir ² , Volodin Alexander ² , Zaikovski Vladimir ² , Sun Naijian ¹ , Klabunde Kenneth J. ¹

Affiliations

1	Department of Chemistry, Kansas State University, Manhattan, KS 66506, USA
2	Boreskov Institute Catalysis, Novosibirsk 630090, Russia

Nanocyrstals of MgO having 4 nm average crystallite sizes with 450–550 m2/g surface area were prepared by the Aero-gel preparation method (AP-MgO). Dehydrohalogenation of 1-chlorobutane was performed using AP-MgO as a catalyst; And 1-butene is the selective product formed even after several cycles of 1-chlorobutane injections. AP-MgO was allowed to react with Cl2, which resulted in the formation of a highly reactive adduct which has a capability to selectively chlorinate propane.

Richards R. , Mulukutla R.S. , Mishakov I. , Chesnokov V. , Volodin A. , Zaikovski V. , Sun N. , Klabunde K.J.
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst
Scripta Materialia. 2001. V.44. N8-9. P.1663-1666. DOI: 10.1016/S1359-6462(01)00877-6 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 21, 2000
Accepted:	Nov 22, 2000
Published print:	May 18, 2001
Published online:	Jun 13, 2001

Web of science:	WOS:000169389400099
Scopus:	2-s2.0-0035906768
Elibrary:	13385558
Chemical Abstracts:	2001:440766
Chemical Abstracts (print):	135:127683
OpenAlex:	W1983987673

DB	Citing
Web of science	37
Scopus	42
Elibrary	40
OpenAlex	44