Thermal Isomerization of α-Pinene in Supercritical Ethanol Научная публикация
| Журнал |
Chemical Engineering Science
ISSN: 0009-2509 , E-ISSN: 1873-4405 |
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| Вых. Данные | Год: 2007, Том: 62, Номер: 9, Страницы: 2414-2421 Страниц : 8 DOI: 10.1016/j.ces.2007.01.041 | ||||
| Ключевые слова | α-pinene, Kinetic model, Model identification, Pressure effect, Supercritical solvents-fluids, Terpene compounds, Transition state | ||||
| Авторы |
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| Организации |
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Реферат:
The experimental study followed by mathematical processing of the data showed that supercritical ethanol is an effective reaction medium for thermal isomerization of α-pinene. Rate of the reaction in supercritical solvent is by several orders of magnitude greater than the rate observed under normal conditions, with selectivity to the target reaction products being retained. The study allowed us for the first time to obtain the kinetic model of α-pinene isomerization in supercritical ethanol that takes into account temperature and pressure effect on the reaction rate and selectivity.
Библиографическая ссылка:
Yermakova A.
, Chibiryaev A.M.
, Kozhevnikov I.V.
, Mikenin P.E.
, Anikeev V.I.
Thermal Isomerization of α-Pinene in Supercritical Ethanol
Chemical Engineering Science. 2007. V.62. N9. P.2414-2421. DOI: 10.1016/j.ces.2007.01.041 WOS Scopus РИНЦ CAPlusCA OpenAlex
Thermal Isomerization of α-Pinene in Supercritical Ethanol
Chemical Engineering Science. 2007. V.62. N9. P.2414-2421. DOI: 10.1016/j.ces.2007.01.041 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 10 апр. 2006 г. |
| Принята к публикации: | 19 янв. 2007 г. |
| Опубликована online: | 4 февр. 2007 г. |
| Опубликована в печати: | 1 мая 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000246492900010 |
| Scopus: | 2-s2.0-33947668295 |
| РИНЦ: | 13554271 |
| Chemical Abstracts: | 2007:367320 |
| Chemical Abstracts (print): | 146:523760 |
| OpenAlex: | W2071431371 |